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In the past few decades, the use of glass in buildings has remarkably increased. As a result, several transparent buildings have been constructed, in which the materials have almost disappeared. Given that the advancement of architecture is inextricably linked to the acquisition of general knowledge on future developments, this study was conducted to predict the paths of development that glass structures are likely to take in the future. Investigations such as this increase the possibility of advancing both design and construction at the same speed as technology. To achieve this goal, this study evaluates the present situation by investigating new possibilities and assessing their effect on the development of glass buildings. The findings of this study show that the durability, safety, appearance, and efficiency of transparent buildings can be improved through continuous refinement of designs, replacement of aged elements, prompt repair of damaged protective coatings, and greater exploitation of double-sided screens.

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This paper explores the self-healing abilty of the ionomer called Surlyn® 8940 (manufactured by DuPont), a partially neutralised poly(ethylene-co-methacrylic acid) (EMAA) ionomer copolymer, and the improvement of the mechanical properties after adding a nano-reinforcement of multiwall carbon nanotubes (MWCNTs) to the structure of the polymer. It begins with the manufacture the nanocomposite material, based on Surlyn® 8940 as raw material, and the mixture process with MWCNTs. Afterwards, an extrusion process was optimized to obtain a homogeneous reinforced filament, which was subsequently used to manufacture the final test samples by means of a 3D printing machine. Specimens with different concentrations of MWCNTs (0.0, 0.1, 0.5, 1.0 % wt.) were manufactured, in order to test the mechanical properties and self-healing ability of unreinforced and nano-reinforced samples. The results show that nano-reinforced samples had an increase of their self-healing ability (increase for 0.5 y el 1% wt. of MWCNTs) and mechanical properties (σ_TS 18.35, 25.91, 26.92, 28.02 MPa to 0, 0.1, 0.5 y 1 % wt. de MWCNTs respectively). Specimens of 5% of MWCNTs have also been manufactured with different mixing times in the extrusion chamber to study the conductivity of the polymer. Electrical conductivity values ​​for 8 and 10 minutes of mixing times reached S/m units order have been obtained.

Abstract

Inspired by some of the mechanisms that occur in nature, self-healing materials are characterized by the ability to recover, partially or totally, their initial properties after suffering damage. These materials constitute an efficient alternative for extending the lifecycle of products, as well as for reducing the amount of waste generated. At the same time, they reduce maintenance and repair costs. In this work, examples of recent developments in the field of elastomeric composite materials are presented, studying different matrices, natural rubber (NR), epoxidized natural rubber (ENR), styrene-butadiene rubber (SBR) and nitrile rubber (NBR), and using diverse repair strategies, hydrogen bonds, disulfide exchange reactions, Diels-Alder chemistry and ionic interactions. The effect of adding carbon-derived reinforcing fillers (graphene oxide) and sustainable alternative fillers (ground tire rubber) is also analyzed. It is studied how the presence and type of filler influences the healing capacity of elastomeric matrices, reaching repair efficiencies of up to ~80%, without detriment to their mechanical performance.

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In this work, the effect of the localization of the catalyst in a self-repairing system based on the microencapsulation technology in a bi-component epoxy adhesive has been studied. The efficiency of a conventional self-healing system (microcapsules + catalyst) has been compared with a system in which the curing agent and the catalyst are in the same microcapsule but isolated from each other. This system has been called "All in one" and has shown to be more efficient than the conventional one, achieving efficiencies of up to 116%.

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This study examined durability of mortar after repairing crack using alginate gel films (1.5wt.%) mixed with healing agents under seawater splayed condition. The healing agents consist of Bacillus subtilis (natto) as an aerobic microorganism and glucose as an organic carbon source, thereby producing insoluble calcium carbonate in the gel films in the presence of calcium ions. In this study, repaired mortar was dried under room condition for half year and exposed at seawater splayed condition for another half year. After that, surface condition, elastic wave velocity was measured. In addition, the inside situation in the crack was observed by X ray computed tomography. Based on the results of elastic wave velocity, the property of repair material in mortar was improved under the seawater splayed condition. Additionally the substance in crack derived from healing agents was remained even after seawater splayed exposure.

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