Abstract

Reprocessable, repairable, and recyclable thermoset composites have the potential to improve the circularity of composites and ensure their sustainability. Disulfide-based epoxy matrices are under development to meet the specifications of key sectors (transport, wind energy, etc.). The manufacturing of reinforced composites by different techniques (infusion, prepregs, etc.) has been validated (TRL 4-5). The incorporation of new functionalities, such as fire resistance, and the validation of recycling are now on the table. Conventional chemical recycling separates the reinforcement from the composite for reuse, leaving aside the polymer matrix. The new functionalities incorporated require recovery and validation of the matrix. Dynamic resins allow milder conditions to be applied during recycling, and the challenge remains to find new applications that reuse these recycled products. On the other hand, the rational use of resources demands for new recycling routes that do not require separation of the components, apply few steps, be economically viable, and maintain the value of the reinforcement and the matrix. Vitrimers allow the thermoforming of composite parts through the application of heat and pressure. This process opens the way from reusing final parts with new shapes to generating short new fibre composites from mechanical pre-crushing. This communication will present the latest developments and objectives of several European projects funded under the HE framework (SURPASS, GA no. 101057901; MC4, GA no. 101057394) in which work on the maturity of the technologies is in progress.

Abstract

Carbon fibre reinforced composites (CFRP) are key in different industrial sectors as they combine lightness and robustness. This circumstance and the growing need to take advantage of the resources of any product, has triggered a strong demand to establish sustainable technological solutions that allow the effective use of composite materials: resins (matrix) and fibres (reinforcement).

Limited to mechanical recycling, recycling alternatives for CFRP with thermosetting resins have focused on thermochemical treatments, usually pyrolysis to recover the fibres, degrading the matrix. In addition to thermal routes, solvent treatments under supercritical conditions have also been studied. However, these processes exclude resin recovery and involve a partial loss of mechanical properties of the fibres due to the heat treatment (450-550 °C).

As an alternative, a solvolysis using mild conditions is proposed to treat CFRPs with amine-hardened epoxy resins, so that the fibres are recovered with all their properties and the organic matrix is materially valorised. This process is applied to reference materials of known composition and validated with real residues with good results in terms of degree of resin decomposition. The recovered fibres show almost resin-free surface and seem to have mechanical properties comparable to those of virgin fibres.