Transforming low-quality sand into construction materials under 110℃ and Recycling of the Waste Solution

Abstract

A strong and eco-friendly material was transformed from low-quality sand via sol-gel method with ethanol as the solvent. 110oC was chosen as a target temperature because it is the average day temperature of the moon, which may be the first place for extraterrestrial development. The appropriate KOH content and ethanol concentration can improve the reaction degree and limit the side reaction. The main results indicated that the highest compressive strength (38 MPa) of the produced material could be obtained by using 20 mass% KOH and 90 V/V% ethanol. According to XRD and FTIR analysis, the formation of sanidine, zeolite, and tetraethoxysilane is the main reason for strength enhancement. Sanidine and zeolite could fill the gap between sand particles and tetraethoxysilane is a good consolidate. Excess ethanol in the waste solution can be reused with recycle rate above 65%. The total carbon emission is 197 kg CO2 eq/m2 after recycling waste solution, which is 35.82% of that produced by normal concrete. Therefore, a tough construction material can be synthesized from lowquality sand, which can partially substitute concrete. This material can address the shortage of raw materials for concrete and can be utilised for extra-terrestrial construction.

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