Effect of Pre-calcination of Lead-zinc Tailings on the Activation of Blast Furnace Slag

Abstract

Blast furnace slag and lead-zinc tailings (LZTs) are solid wastes from the iron-making and mining industries, respectively. In order to reuse these solid wastes, the LZTs were pre-calcined at different temperatures and then explored whether it is capable of being the activator of slag. The effects of pre-calcination on the phase composition of LZTs were elucidated by XRD. The compressive strength of LZTs-activated slag pastes was investigated, and the mineral composition and microstructure of the pastes were detected by XRD and SEM. The results imply that with the elevating of heating temperature from 500 ℃ to 1000 ℃, the dolomite in LZTs decompose into CaO and MgO, and the oxidation of pyrite resulted in the formation of Fe2O3 and gaseous SO3, then SO3 reacted with a part of formed CaO to produce CaSO4. The resulting CaSO4 and CaO can become the sulfate activator and alkaline activator of slag, respectively. The LZTs-activated slag pastes prepared with the LZTs preheated at 800 ℃ exhibit the highest strength at 90 d, which yield 24 MPa. The hydration products of LZTs-activated slag were ettringite and calcium silicate hydrates (C-S-H gel). Large amounts of dense C-S-H gel bond together, connecting most of the ettringite networks into a whole, thus forming a dense structure and effectively improving the strength of LZTs-activated slag. The outcome of this study provides a potential disposing or reusing approach of the large amounts of LZTs.

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