Abstract

The degradation of concrete due to sulfate attack from internal or external sources is a serious problem. The cause of this degradation is the formation and growth of ettringite, which results from the reaction of cement hydrates with sulfate ions in the pore network. This crystal growth leads to a pore pressure that can exceed the concrete’s strength. This paper presents a modeling of concrete’s sulfate-induced stress-strain behavior based on damage poromechanics and two kinetic laws for ettringite growth. Free expansion of cement paste samples exposed to sulfate solutions were measured, and mercury porosimetry tests were conducted at different expansion stages. The pore size distribution was analyzed to locate the dissolution of hydrates and precipitation of ettringite at the pore scale. Results support the theory that ettringite first precipitates in larger capillary pores and spreads to smaller ones. A heat-based dissolution test was performed at different expansion stages, revealing ettringite formed in the pore size range of 4-30 nm. The model was implemented in a finite volume code and applied to four experimental cases from the literature: ESA and DEF in confined and free conditions. The kinetic coefficients were calibrated to fit the observed strains in some experiments and used to blindly test the model in others. Diffusion was neglected due to the small sample size. All simulations showed that the calibrated kinetic parameters had the same order of magnitude, supporting the right physics involved