Abstract

Rice straw is a problematic agricultural waste that is currently burnt in tonnes in the Albufera de Valencia after the harvest, with the consequent environmental damage. In this sense, to avoid wasting resources and unnecessary pollution, it is proposed to revalue the product, that is, to use rice straw, as a source of lignin and cellulose, for the development of materials for footwear, such as soles, insoles, or adhesives. The extraction of cellulose fibres from rice straw is done by physical and/or chemical processes, such as: hydrothermal steam treatment (steam explosion); alkaline treatment, peroxides, and bleaching. The extraction method is optimised by combining processes to maximise the yield obtained. To do this, the processing conditions of each of the extraction stages are varied, optimising variables such as: temperature, time, CO2 pressure, among others. Furthermore, through the use of lignin, also present in rice straw, it is possible to produce polyols to synthesise adhesives, achieving a complete revaluation of rice straw. Therefore, this study aims to determine the effect of rice straw processing conditions on the cellulose extraction yield by optimising the hydrothermal process, pre- and post-processing, as well as on the properties of the cellulose fibres, in addition to the extraction of lignin for its future use as a raw material for the production of polyols and synthesis of adhesives.

Abstract

This study experimentally analyses the phenomenon of delamination under static and fatigue loading in mode II using the standardized End-Notched Flexure (ENF) test. Adhesive joints made of two epoxy matrix laminates reinforced with unidirectional carbon fiber are studied, bonded with an epoxy adhesive, and subjected to environmental degradation in a saline environment for exposure periods of 1, 2, 4, and 12 weeks.

By conducting initial static tests on the joints, we identified crucial values for the rate at which energy is released under mode II conditions. These values served as a benchmark to establish the approach for dynamic fatigue testing. Our objective was to generate characteristic curves that illustrate how these adhesive joints behave when fatigue delamination begins, while also assessing the impact of varying exposure periods on their performance. To enhance result interpretation, we employed a probabilistic model rooted in the Weibull distribution to analyse the experimental data.

The results show that adhesive joints experience a decrease in their delamination resistance when exposed to a saline environment.

Abstract

One of the main advantages of using reinforced thermoplastic materials is the possibility of joining different parts by welding. Welding process avoids the use of mechanical joints, which increase the weight of the component and the manufacturing time; as well as adhesive joints, where it is difficult to ensure their quality.

Welded joints are of special interest when applied in assembly processes with a high production rate. However, welded joints on high-rate components require research into new materials, processes, and inspection techniques. In this line, the present work analyzes the results obtained from different welded joints through heating by electrical resistance without contact. This characterization study includes mechanical, microstructural and physical-chemical properties analysis, as well as its evaluation through non-destructive inspection techniques. As a result, a deeper knowledge of the materials and processes has been obtained, including the effect of the different welding processing parameters.

Different opening mode mechanical tests are presented in this study, as well as thermal analysis by differential scanning calorimetry to evaluate the effect of temperature and time applied during the welding process on the final properties. The quality of the process in the different joining elements has been verified with inspection by means of infrared thermography, correlating indications in the level of IR radiation with localized variations microscopy features (i.e.: amount of resin). In addition, a microstructural study has been carried out to assess the fiber/resin content of the material in the joint areas, as well as a complementary analysis using computed tomography and ultrasound.