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Orue et al 2019a - Revision history
2026-04-21T16:19:29Z
Revision history for this page on the wiki
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Materiales.Compuestos at 10:16, 23 October 2022
2022-10-23T10:16:55Z
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<td colspan='2' style="background-color: white; color:black; text-align: center;">Revision as of 10:16, 23 October 2022</td>
</tr><tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l68" >Line 68:</td>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div><span style="text-align: center; font-size: 75%;">'''Figure 2'''. Espectros de FTIR: (a) PLA, (b) PLA/SBO y (c) PLA/ESBO</span></div></div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div><span style="text-align: center; font-size: 75%;">'''Figure 2'''. Espectros de FTIR: (a) PLA, (b) PLA/SBO y (c) PLA/ESBO</span></div></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div>'''3.3''' Calorimetría diferencial de barrido</div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins class="diffchange diffchange-inline">===</ins>'''3.3''' Calorimetría diferencial de barrido<ins class="diffchange diffchange-inline">===</ins></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>Tabla 1 muestra los valores obtenidos de las termogramas de DSC, así como el grado de cristalinidad del PLA y mezclas plastificadas con aceites vegetales después del 2<sup>ndo</sup> barrido.</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>Tabla 1 muestra los valores obtenidos de las termogramas de DSC, así como el grado de cristalinidad del PLA y mezclas plastificadas con aceites vegetales después del 2<sup>ndo</sup> barrido.</div></td></tr>
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Materiales.Compuestos
https://www.scipedia.com/wd/index.php?title=Orue_et_al_2019a&diff=258353&oldid=prev
Materiales.Compuestos at 10:16, 23 October 2022
2022-10-23T10:16:21Z
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<td colspan='2' style="background-color: white; color:black; text-align: center;">Revision as of 10:16, 23 October 2022</td>
</tr><tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l54" >Line 54:</td>
<td colspan="2" class="diff-lineno">Line 54:</td></tr>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><span style="text-align: center; font-size: 75%;">'''Figure 1.  '''(a) Deformación a la rotura, (b) módulo de Young, (c) resistencia a tracción y (d) resistencia al impacto de los sistemas.</span></div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins class="diffchange diffchange-inline"><div class="center" style="width: auto; margin-left: auto; margin-right: auto;"></ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><span style="text-align: center; font-size: 75%;">'''Figure 1.  '''(a) Deformación a la rotura, (b) módulo de Young, (c) resistencia a tracción y (d) resistencia al impacto de los sistemas.</span<ins class="diffchange diffchange-inline">></div</ins>></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>Observando los valores de resistencia al impacto, Figura 1d, las mezclas plastificadas mostraron valores de resistencia al impacto más altas que el propio polímero de PLA indicando que los plastificantes mejoraron la movilidad de las cadenas de PLA.</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>Observando los valores de resistencia al impacto, Figura 1d, las mezclas plastificadas mostraron valores de resistencia al impacto más altas que el propio polímero de PLA indicando que los plastificantes mejoraron la movilidad de las cadenas de PLA.</div></td></tr>
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<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div><div class="center" style="width: auto; margin-left: auto; margin-right: auto;">[[File:Orue_et_al_2019a-image9-c.png|centre|473x473px]]</div></div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div><div class="center" style="width: auto; margin-left: auto; margin-right: auto;">[[File:Orue_et_al_2019a-image9-c.png|centre|473x473px]]</div></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;"></ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;"><div class="center" style="width: auto; margin-left: auto; margin-right: auto;"></ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><ins style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">'''Figure 2'''. Espectros de FTIR: (a) PLA, (b) PLA/SBO y (c) PLA/ESBO</span></div></ins></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>'''3.3''' Calorimetría diferencial de barrido</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>'''3.3''' Calorimetría diferencial de barrido</div></td></tr>
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Materiales.Compuestos
https://www.scipedia.com/wd/index.php?title=Orue_et_al_2019a&diff=258352&oldid=prev
Materiales.Compuestos at 10:14, 23 October 2022
2022-10-23T10:14:38Z
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<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><div class="center" style="width: auto; margin-left: auto; margin-right: auto;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">A. Orue, A. Eceiza, C. Peña-Rodriguez, A. Arbelaiz </div></del></div></td><td colspan="2"> </td></tr>
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<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><div class="center" style="width: auto; margin-left: auto; margin-right: auto;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Departamendo de Ingeniería Quimica y Medio Ambiente, Grupo de Investigacion “Materiales + Tecnologias”, </span></div></del></div></td><td colspan="2"> </td></tr>
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<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><div class="center" style="width: auto; margin-left: auto; margin-right: auto;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Universidad del País Vasco/Euskal Herriko Unibertsitatea, Donostia, 20018, España</span></div></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">{| style="width: 87%;border-collapse: collapse;" </del></div></td><td colspan="2"> </td></tr>
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<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  colspan='2'  style="vertical-align: top;"|<big>Estudio de los sistemas basados en poliácido láctico                            y aceites vegetales </big></del></div></td><td colspan="2"> </td></tr>
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<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  style="border-top: 1pt solid black;border-bottom: 1pt solid black;vertical-align: top;"|<span style="text-align: center; font-size: 75%;">Historia del artículo:</span></del></div></td><td colspan="2"> </td></tr>
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<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Recibido 5 de Mayo 2017</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">En la versión revisada 5 de Mayo 2017</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Aceptado 31 de Mayo 2017</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Accesible online 21 de Junio 2017</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  rowspan='4' style="vertical-align: top;"|<span style="text-align: center; font-size: 75%;">Debido a la alta fragilidad que presenta el poli (ácido láctico) (PLA), el objetivo principal del trabajo es la obtención de un material más dúctil, y su posterior caracterización mediante diferentes técnicas. Con el objetivo de plastificar el PLA, se han utilizado plastificantes provenientes de recursos renovables, como son los aceites vegetales de soja epoxidados y sin epoxidar. El PLA se ha plastificado con una concentración de 20% en peso de aceite y se han estudiado las propie</span><span style="text-align: center; font-size: 75%;">dades de las diferentes mezclas. Los ensayos de impacto demostraron que el PLA se volvió más dúctil con la adición de los plastificantes. Además, los sistemas modificados con aceites epoxidados mostraron una mayor resistencia a tracción y al impacto. Gracias a la espectroscopia infrarroja de transformada de Fourier (FTIR), se pudo observar que la banda relacionada con el grupo epoxi no desapareció completamente sugiriendo así una reacción incompleta entre el grupo funcional de los aceites funcionales y el grupo funcional del PLA. Por último, mediante la técnica de calorimetría diferencial de barrido (DSC) se ha observado que tras la adición de los aceites vegetales, tanto la temperatura de transición vítrea (</span><span style="text-align: center; font-size: 75%;">T<sub>g</sub></span><span style="text-align: center; font-size: 75%;">) como la temperatura de la cristalización fría (T<sub>cc</sub></span><span style="text-align: center; font-size: 75%;">) del PLA disminuyó considerablemente.</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|-</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  style="border-top: 1pt solid black;vertical-align: top;"|<span style="text-align: center; font-size: 75%;">Palabras clave:</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Poliácido láctico</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Aceites vegetales</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Miscibilidad</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Plastificación</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|-</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  style="border-top: 1pt solid black;vertical-align: top;"|</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|-</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  colspan='2'  style="vertical-align: top;"|<big>Study of blends based on poly (lactic acid)                                          and vegetable oils </big></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|-</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  style="border-bottom: 1pt solid black;vertical-align: top;"|<span style="text-align: center; font-size: 75%;"> [[Image:Orue_et_al_2019a-image2.png|54px]] </span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  style="vertical-align: top;"|</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|-</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  style="border-top: 1pt solid black;border-bottom: 1pt solid black;vertical-align: top;"|<span style="text-align: center; font-size: 75%;">Keywords:</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Poly(lactic acid) </span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Vegetable oils</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Miscibility</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"><span style="text-align: center; font-size: 75%;">Plasticization </span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  rowspan='2' style="vertical-align: top;"|<span style="text-align: center; font-size: 75%;">Due to the high brittleness of the poly (lactic acid) (PLA), the main purpose of this work is to obtain a more ductile material than neat PLA, and the subsequent characterization by different techniques. In order to plasticize neat PLA, some plasticizers from renewable resources, such as non-epoxidized and epoxidized and soybean oils, have been used. Neat PLA has been plasticized with 20 wt% of plasticizers and the properties of different blends have been studied. Impact test results have showed that PLA became more ductile with the addition of vegetable oils. Furthermore, PLA/epoxidized vegetable oil blends showed higher tensile and impact strength values than that for blends plasticized with non-epoxidized oils. Fourier transform infrared spectroscopy (FTIR) technique has showed that the </span><span style="text-align: center; font-size: 75%;">band related to the epoxy group did not completely disappear in the spectra of PLA/epoxidized vegetal oil suggesting an incomplete reaction between the epoxy group of epoxidized vegetable oils and the functional groups of PLA. Finally, by differential scanning calorimetry (DSC) technique has observed that after the addition of vegetable oils, both the glass transition temperature (T<sub>g</sub></span><span style="text-align: center; font-size: 75%;">) and the cold crystallization temperature (T<sub>cc</sub></span><span style="text-align: center; font-size: 75%;">) values of the neat poly (lactic acid) were decreased considerably.</span></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|-</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|  style="border-top: 1pt solid black;vertical-align: top;"|</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;">|}</del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del style="font-weight: bold; text-decoration: none;"></del></div></td><td colspan="2"> </td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==1 Introducción==</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>==1 Introducción==</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l125" >Line 125:</td>
<td colspan="2" class="diff-lineno">Line 62:</td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div><span id='_Ref480281235'></span>Figura 2 muestra los espectros de FTIR del polímero PLA y mezclas plastificadas con 20% en peso de aceites vegetales. En el caso de PLA, las bandas situadas a 2994, 2944 y          1747 cm<sup>-1</sup> fueron asignados a la vibración de estiramiento del  –CH2 y vibración de los enlaces –C=O, respectivamente, [<span id='cite-_Ref480280744'></span>[[#_Ref480280744|5]],<span id='cite-_Ref480280882'></span>[[#_Ref480280882|10]],<span id='cite-11'></span>[[#11|11]]] mientras que las bandas situadas a 1180 y 1078 cm<sup>-1 </sup>fueron asignadas al estiramiento de C-O del grupo terminal del PLA [<span id='cite-_Ref480281037'></span>[[#_Ref480281037|8]]]. Para las mezclas plastificadas con aceites vegetales se observó que las situadas a 2944 y 1078 cm<sup>-1</sup> del PLA se desplazaron a 2942 y 1079 cm<sup>-1</sup>, respectivamente. Los desplazamientos en las bandas del absorción del PLA pueden indicar cierta interacción entre el PLA y los plastificantes [<span id='cite-_Ref480280882'></span>[[#_Ref480280882|10]]]. Además, observando los espectros de las mezclas plastificadas, se apreciaron nuevas bandas de absorción en el intervalo de 3050-2800 cm<sup>-1</sup> relacionadas con los plastificantes. Por último, en el espectro FTIR de la mezcla PLA/ESBO se observó la característica banda a 823 cm<sup>-1</sup> del grupo epoxi lo cual puede indicar que el grupo epoxi del aceite epoxidado de soja no pudo reaccionar íntegramente con los grupos funcionales del PLA.</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div><span id='_Ref480281235'></span>Figura 2 muestra los espectros de FTIR del polímero PLA y mezclas plastificadas con 20% en peso de aceites vegetales. En el caso de PLA, las bandas situadas a 2994, 2944 y          1747 cm<sup>-1</sup> fueron asignados a la vibración de estiramiento del  –CH2 y vibración de los enlaces –C=O, respectivamente, [<span id='cite-_Ref480280744'></span>[[#_Ref480280744|5]],<span id='cite-_Ref480280882'></span>[[#_Ref480280882|10]],<span id='cite-11'></span>[[#11|11]]] mientras que las bandas situadas a 1180 y 1078 cm<sup>-1 </sup>fueron asignadas al estiramiento de C-O del grupo terminal del PLA [<span id='cite-_Ref480281037'></span>[[#_Ref480281037|8]]]. Para las mezclas plastificadas con aceites vegetales se observó que las situadas a 2944 y 1078 cm<sup>-1</sup> del PLA se desplazaron a 2942 y 1079 cm<sup>-1</sup>, respectivamente. Los desplazamientos en las bandas del absorción del PLA pueden indicar cierta interacción entre el PLA y los plastificantes [<span id='cite-_Ref480280882'></span>[[#_Ref480280882|10]]]. Además, observando los espectros de las mezclas plastificadas, se apreciaron nuevas bandas de absorción en el intervalo de 3050-2800 cm<sup>-1</sup> relacionadas con los plastificantes. Por último, en el espectro FTIR de la mezcla PLA/ESBO se observó la característica banda a 823 cm<sup>-1</sup> del grupo epoxi lo cual puede indicar que el grupo epoxi del aceite epoxidado de soja no pudo reaccionar íntegramente con los grupos funcionales del PLA.</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><div class="center" style="width: auto; margin-left: auto; margin-right: auto;"></div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><div class="center" style="width: auto; margin-left: auto; margin-right: auto;">[[<ins class="diffchange diffchange-inline">File</ins>:Orue_et_al_2019a-image9-c.png|<ins class="diffchange diffchange-inline">centre|473x473px</ins>]]</div></div></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><del class="diffchange diffchange-inline"> </del>[[<del class="diffchange diffchange-inline">Image</del>:Orue_et_al_2019a-image9-c.png|<del class="diffchange diffchange-inline">276px</del>]] </div></div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>'''3.3''' Calorimetría diferencial de barrido</div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>'''3.3''' Calorimetría diferencial de barrido</div></td></tr>
<tr><td colspan="2" class="diff-lineno" id="mw-diff-left-l145" >Line 145:</td>
<td colspan="2" class="diff-lineno">Line 81:</td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div><div class="center" style="width: auto; margin-left: auto; margin-right: auto;"></div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div><div class="center" style="width: auto; margin-left: auto; margin-right: auto;"></div></td></tr>
<tr><td class='diff-marker'>−</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #ffe49c; vertical-align: top; white-space: pre-wrap;"><div><span style="text-align: center; font-size: 75%;">'''Tabla 1. '''Valores de T<sub>g</sub>, T<sub>cc</sub> y T<sub>m</sub>, entalpías de los procesos de la cristalización fría y fusión y grado de cristalinidad del PLA y mezclas plastificadas<del class="diffchange diffchange-inline">.</del></span></div></div></td><td class='diff-marker'>+</td><td style="color:black; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #a3d3ff; vertical-align: top; white-space: pre-wrap;"><div><span style="text-align: center; font-size: 75%;">'''Tabla 1. '''Valores de T<sub>g</sub>, T<sub>cc</sub> y T<sub>m</sub>, entalpías de los procesos de la cristalización fría y fusión y grado de cristalinidad del PLA y mezclas plastificadas</span></div></div></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"></td></tr>
<tr><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>{| style="width: 100%;margin: 1em auto 0.1em auto;border-collapse: collapse;"  </div></td><td class='diff-marker'> </td><td style="background-color: #f9f9f9; color: #333333; font-size: 88%; border-style: solid; border-width: 1px 1px 1px 4px; border-radius: 0.33em; border-color: #e6e6e6; vertical-align: top; white-space: pre-wrap;"><div>{| style="width: 100%;margin: 1em auto 0.1em auto;border-collapse: collapse;"  </div></td></tr>
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2022-05-07T10:38:48Z
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Scipediacontent: Scipediacontent moved page Draft Content 818539903 to Orue et al 2019a
2022-03-31T18:49:57Z
<p>Scipediacontent moved page <a href="/public/Draft_Content_818539903" class="mw-redirect" title="Draft Content 818539903">Draft Content 818539903</a> to <a href="/public/Orue_et_al_2019a" title="Orue et al 2019a">Orue et al 2019a</a></p>
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Scipediacontent: Created page with "== Abstract == Due to the high brittleness of the poly (lactic acid) (PLA), the main purpose of this work is to obtain a more ductile material than neat PLA, and the subseque..."
2022-03-31T18:49:54Z
<p>Created page with "== Abstract == Due to the high brittleness of the poly (lactic acid) (PLA), the main purpose of this work is to obtain a more ductile material than neat PLA, and the subseque..."</p>
<p><b>New page</b></p><div>== Abstract ==<br />
<br />
Due to the high brittleness of the poly (lactic acid) (PLA), the main purpose of this work is to obtain a more ductile material than neat PLA, and the subsequent characterization by different techniques. In order to plasticize neat PLA, some plasticizers from renewable resources, such as non-epoxidized and epoxidized and soybean oils, have been used. Neat PLA has been plasticized with 20 wt% of plasticizers and the properties of different blends have been studied. Impact test results have showed that PLA became more ductile with the addition of vegetable oils. Furthermore, PLA/epoxidized vegetable oil blends showed higher tensile and impact strength values than that for blends plasticized with non-epoxidized oils. Fourier transform infrared spectroscopy (FTIR) technique has showed that the band related to the epoxy group did not completely disappear in the spectra of PLA/epoxidized vegetal oil suggesting an incomplete reaction between the epoxy group of epoxidized vegetable oils and the functional groups of PLA. Finally, by differential scanning calorimetry (DSC) technique has observed that after the addition of vegetable oils, both the glass transition temperature (Tg) and the cold crystallization temperature (Tcc) values of the neat poly (lactic acid) were decreased considerably.<br />
<br />
== Full document ==<br />
<pdf>Media:Draft_Content_818539903native-articles-203.pdf</pdf></div>
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