Scipedia: Collection of Energy Science & Engineering

Use of nonimmobilized enzymes and mediators achieved high power densities in closed biobatteries

Scipedia content — Thu, 01 Jun 2017 14:59:01 +0200

The immobilization of redox enzymes on the surface of electrodes is a typical practice for enzymatic fuel cells (EFCs) but enzyme immobilization usually results in low retaining enzymatic activities and low power densities. Here, we investigated an alternative solution – the use of nonimmobilized thermostable enzymes (e.g., NAD-based glucose 6-phosphate dehydrogenase and flavin-containing diaphorase) and a nonimmobilized mediator (i.e., benzyl viologen or 9, 10-anthraquinone-2, 7-disulphonic acid, AQDS) for achieving high power densities from glucose 6-phosphate in closed EFCs (called biobatteries). At the same enzyme loading, power densities of biobatteries increased in an order from the case of immobilized enzymes and immobilized vitamin K3 to the case of nonimmobilized enzymes and immobilized vitamin K3 to the case of nonimmobilized enzymes and nonimmobilized AQDS. The maximum power density of the biobattery based on nonimmobilized enzymes and AQDS was 1.1 mW cm−2 of anode at room temperature, 34-times of the biobattery based on immobilized enzymes and immobilized vitamin K3. When enzyme loading was increased by another 10-fold, the highest power density of biobattery was increased to 2.4 mW cm−2 at 37°C. The biobattery based on nonimmobilized enzymes and AQDS retained 60% of its initial current density after running for 2 h. When repeatedly being used for 6 rounds, the biobattery had 35% of its initial current density after 12 days. Our results suggest that closed biobatteries equipped with nonimmobilized thermostable enzymes and mediators feature simple system configuration and have high power densities.

Study of a new hydraulic pumping unit based on the offshore platform

Scipedia content — Thu, 01 Jun 2017 14:58:42 +0200

This article introduces a new technology about a rod pumping in the offshore platform according to the demand of offshore heavy oil thermal recovery and the production of stripper well, analyzes the research status of hydraulic pumping unit at home and abroad, and designs a new kind of miniature hydraulic pumping unit with long-stroke, low pumping speed and compact structure to resolve the problem of space limitation. The article also describes the whole structure and the working principle of this pumping unit, determines the choice of stroke and rate of the pumping unit, and establishes mathematical models based on the polished rod loads. A new composite hydraulic cylinder with a special structure was designed by combining the hydraulic cylinder with the energy accumulator. This composite hydraulic cylinder is applied on land, and the model prototype runs smoothly, which indicates that the whole structure design of the pumping unit is reasonable and the control strategy is correct.

Marginal abatement cost curve for wind power in China: a provincial-level analysis

Scipedia content — Thu, 01 Jun 2017 14:57:44 +0200

Wind power has seen a remarkable growth in China since the Renewable Energy Law came into force in the beginning of 2006. However, the contribution and the economic cost of wind power development to reduce carbon emission at the provincial level are still unclear. This research combined geographic information system analysis and levelized production cost calculation to provide provincial-level supply curve of carbon dioxide (CO2) mitigation by wind power in China. The results showed that wind power could be a very competitive mitigation option in China, with a potential to contribute 500 million tons of CO2 emission mitigation at an average abatement cost of 75 RMB/t of CO2 mitigation. The emission abatement cost and the potential to reduce carbon emission in different provinces may be used for national planning as well as for the allocation of investments.

Design of photovoltaics for modules with 50% efficiency

Scipedia content — Thu, 01 Jun 2017 14:57:33 +0200

We describe a spectrum splitting solar module design approach using ensembles of 2–20 subcells with bandgaps optimized for the AM1.5D spectrum. Device physics calculations and experimental data determine radiative efficiency parameters for III-V compound semiconductor subcells and enable modification of conventional detailed balance calculations to predict module efficiency while retaining computational speed for a wide search of the design space. Accounting for nonideal absorption and recombination rates due to realistic material imperfections allows us to identify the minimum subcell quantity, quality, electrical connection configuration, and concentration required for 50% module efficiency with realistic optical losses and modeled contact resistance losses. We predict a module efficiency of 50% or greater will be possible with 7–10 electrically independent subcells in a spectral splitting optic at 300–500 suns concentration, assuming a 90% optical efficiency and 98% electrical efficiency, provided the subcells can achieve an average external radiative efficiency of 3–5% and a short circuit current that is at least 90% of the ideal. In examining spectrum splitting solar cells with both series-connected and electrically independent subcells, we identify a new design trade-off independent of the challenges of fabricating optimal bandgap combinations. Series-connected ensembles, having a single set of electrical contacts, are less sensitive to lumped series resistance losses than ensembles where each subcells are contacted independently. By contrast, ensembles with electrically independent subcells can achieve lower radiative losses when the subcells are designed for good optical confinement. Distributing electrically independent subcells in a concentrating receiver module allows flexibility in subcell selection and fabrication, and can achieve ultra-high efficiency with conventional III-V cell technology.

Energy production advantage of independent subcell connection for multijunction photovoltaics

Scipedia content — Thu, 01 Jun 2017 14:57:22 +0200

Increasing the number of subcells in a multijunction or “spectrum splitting” photovoltaic improves efficiency under the standard AM1.5D design spectrum, but it can lower efficiency under spectra that differ from the standard if the subcells are connected electrically in series. Using atmospheric data and the SMARTS multiple scattering and absorption model, we simulated sunny day spectra over 1 year for five locations in the United States and determined the annual energy production of spectrum splitting ensembles with 2–20 subcells connected electrically in series or independently. While electrically independent subcells have a small efficiency advantage over series-connected ensembles under the AM1.5D design spectrum, they have a pronounced energy production advantage under realistic spectra over 1 year. Simulated energy production increased with subcell number for the electrically independent ensembles, but it peaked at 8–10 subcells for those connected in series. Electrically independent ensembles with 20 subcells produce up to 27% more energy annually than the series-connected 20-subcell ensemble. This energy production advantage persists when clouds are accounted for.

Status and future strategies for Concentrating Solar Power in China

Scipedia content — Thu, 01 Jun 2017 14:57:13 +0200

China is the world leader in several areas of clean energy, but not in Concentrating Solar Power (CSP). Our analysis provides an interesting viewpoint to Chinas possible role in helping with the market breakthrough of CSP. We present a short overview of the state-of-the-art of CSP including the status in China. A blueprint for Chinas CSP development is elaborated based on Chinas 13th 5-year program, but also on Chinas previous success factors in PV and wind power. The results of this study suggest that China could play a more prominent global role in CSP, but this would require stronger efforts in several areas ranging from innovation to policies.

Tracing the energy footprints of Indonesian manufacturing industry

Scipedia content — Thu, 01 Jun 2017 14:57:02 +0200

The low energy efficiency is the source of the large energy consumption issue and the rapid growth of energy demand in the manufacturing industry sector in Indonesia. The driving forces behind the low energy efficiency situation in this sector are both economic and efficiency factors. The objective of this study is to generate the map of the energy flow in the manufacturing industry sector to investigate the energy utilization in the industrial process. The data sample that represents 80% of energy consumption in the manufacturing sector is used to generate this map. The generated map shows the heating system is the largest energy consumer among all energy equipment and as the primary source of the energy losses. Additionally, we found the industry groups such as sugar, cement, pulp and paper, and textile use enormous amounts of energy as their source for the heating system, meanwhile, the industries such as basic chemical, metal, and textile are the largest electricity consumers for their motor-driven machinery. The energy flow analysis together with the comparison of the Specific Energy Consumption shows the areas that should be the focus for further energy conservation measures. Recommended measures are also discussed.

Lock-in thermography as a tool for quality control of photovoltaic modules

Scipedia content — Thu, 01 Jun 2017 14:56:52 +0200

In this short communication, we present a method which utilizes contactless ILIT (illuminated lock-in thermography) measurement of a photovoltaic (PV) module and image postprocessing in order to calculate the peak power Pmpp of the module and to study the influence of local defects on the module performance. In total, 103 Copper-Indium-Gallium-Diselenide (CIGS) modules were investigated and the results showed a good correlation (mean error less than 6%) between the calculated IR-signal and the measured Pmpp. We performed our study on CIGS modules but the presented approach is not restricted to CIGS modules. The method provides a valuable tool for PV quality control.

Reactivity of CaO with CO2 in molten CaF2–NaF: formation and decomposition of carbonates

Scipedia content — Thu, 01 Jun 2017 14:56:42 +0200

The characteristics of CO2 reacting with CaO in a molten eutectic mixture of CaF2 and NaF has been investigated. Calculations of the Gibbs free energy, temperature analysis of the decomposition of the formed carbonates, and XRD analyses of quenched samples taken during CO2 absorption or desorption were employed to identify the phases present in the melt. Efficient CO2 absorption from a simulated flue gas was observed, due to a combined reaction where CaO initially reacts with CO2 and forms CaCO3. Subsequently, Na2CO3 is formed by an ion exchange reaction between CaCO3 and NaF. It was found that the CaO activity is highest in the temperature range 826–834°C. Increasing the CaO concentration from 5 to 20 wt% in the molten salt resulted in reduced CO2 reactivity efficiency, probably because of precipitation and agglomeration of the sorbent. The total carbonation conversion was independent of the CO2 concentration in the inlet gas, and the sorbent carrying capacity was in the range 0.722–0.743 g CO2/g CaO corresponding to 0.037–0.144 g CO2/g total liquid. Decarbonation was conducted by raising the temperature. 40% conversion back to CaO was recorded at 1160°C. The recorded curves for the CO2 concentration in the outlet gas exhibited a rapid desorption step followed by a slow step.

Cover Image

Scipedia content — Thu, 01 Jun 2017 14:56:32 +0200

The cover image, by Allison Tolbert and Arthur J. Ragauskas, is based on the Review Advances in understanding the surface chemistry of lignocellulosic biomass via time-of-flight secondary ion mass spectrometry, DOI: 10.1002/ese3.144. The authors would like to acknowledge the following image contributors: Robert Davies (Renewable Bioproducts Institute, Georgia Tech) greatly assisted with the image formatting, Wellington Muchero and Jay Chen (Oak Ridge National Laboratory) and Bruce Arey (Environmental Molecular Science Laboratory) provided the Helium Ion Microscope image of Populus cell walls, and Chang Geun Yoo (Oak Ridge National Laboratory) assisted with the creative design.

Advances in understanding the surface chemistry of lignocellulosic biomass via time-of-flight secondary ion mass spectrometry

Scipedia content — Thu, 01 Jun 2017 14:56:21 +0200

Overcoming the natural recalcitrance of lignocellulosic biomass is necessary in order to efficiently convert biomass into biofuels or biomaterials and many times this requires some type of chemical pretreatment and/or biological treatment. While bulk chemical analysis is the traditional method of determining the impact a treatment has on biomass, the chemistry on the surface of the sample can differ from the bulk chemistry. Specifically, enzymes and microorganisms bind to the surface of the biomass and their efficiency could be greatly impacted by the chemistry of the surface. Therefore, it is important to study and understand the chemistry of the biomass at the surface. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a powerful tool that can spectrally and spatially analyze the surface chemistry of a sample. This review discusses the advances in understanding lignocellulosic biomass surface chemistry using the ToF-SIMS by addressing the instrument parameters, biomass sample preparation, and characteristic lignocellulosic ion fragmentation peaks along with their typical location in the plant cell wall. The use of the ToF-SIMS in detecting chemical changes due to chemical pretreatments, microbial treatments, and physical or genetic modifications is discussed along with possible future applications of the instrument in lignocellulosic biomass studies.

In situ synchrotron-based X-ray powder diffraction and micro-Raman study of biomass and residue model compounds at hydrothermal conditions

Scipedia content — Thu, 01 Jun 2017 14:56:11 +0200

The applications of synchrotron X-ray powder diffraction (XRPD) and laser micro-Raman techniques in an examination of the dissolution, transformation, and gasification of pure cellulose and models for biomass residue under hydrothermal conditions in a diamond-anvil cell are reported. The results contribute to the measurement of in situ time-resolved profiles of biomass reactions, catalyst stability, and residue formation that occur in aqueous fluids at near- and supercritical conditions.

Fuzzy ARTMAP and GARCH-based hybrid model aided with wavelet transform for short-term electricity load forecasting

Scipedia content — Thu, 01 Jun 2017 14:56:01 +0200

With the evolution of the electricity market into a restructured smart version, load forecasting has emerged as an eminent research domain. Many forecasting models have been proposed by researchers for electricity price and load forecasting. This state of art introduces a load time series modeled with a hybrid technique culminating from the logical amalgamation of GARCH, a conventional hard computing method, Fuzzy ARTMAP, an artificial intelligence-based soft computing technique, and wavelet transform, for treating the load time series. The study investigates into the ability of the proposed hybrid model in tackling the electricity load time series forecasting problems. The work under this study also includes comparisons drawn among models which use either one or two of the mentioned techniques and the model proposed. Results certify the efficacy and effectiveness of the model over others.

Three-dimensional energetic and exergetic analysis of the injection orientation of DI diesel engine under different engine speeds

Scipedia content — Thu, 01 Jun 2017 14:55:48 +0200

Three-dimensional (3-D) computational code was implemented to solve conservation equations based on finite volume method as to simulate 1.8 L Ford diesel engine. Velocity and pressure of each computational cell is achieved by SIMPLE (semi-implicit method for pressure-linked equations) algorithm. For the exergetic aspect, the initial condition is set at 0.1 MPa and 300 K. The engine modeling is performed with 130 °, 140 °, and 150 ° with respect to x-axis under 1500 and 2500 rpm engine speeds. The results, however, indicate better air/fuel mixture (near stoichiometric equivalence ratio) for 130 ° of injection angle, albeit smaller spray droplets (lower sauter mean diameter) were introduced with 140 °. It is seen that higher soot and NOx mass fraction is attributed to 1500 rpm engine speed. The highest NOx and soot are exhausted at 130 ° and 150 ° of injection, respectively. Second law efficiency was calculated for different spray angle and engine speed schemes such that 36.62%, 30.2%, and 32.07% are associated with 130 °, 140 °, and 150 ° of injection angle under 1500 rpm, respectively. In terms of engine performance, that is, indicated mean effective pressure, indicated specific fuel consumption, and temperature, the best performance metrics are of 130 ° equal to 15.4 bar, 0.3856 kg/kW-h, and 2074.97 K under 1500 rpm, respectively. Instant irreversibility rate is the highest amount with peak value of 17.48 J/deg for 130 deg-1500 rpm, while 140 ° shows higher mean irreversibility rate over crank angle (CA) period.

Shale gas in North America and Europe

Scipedia content — Thu, 01 Jun 2017 14:54:57 +0200

According to the U.S. Energy Information Administration, shale gas will provide half of the United States’ domestic gas by 2035. The United States has already moved from being one of the worlds largest importers of gas to being self-sufficient in less than a decade, bringing hundreds of thousands of jobs and attracting back companies that long ago left America in search of cheap manufacturing costs. But the increase in shale gas extraction has also had an environmental cost. There is clear scientific evidence of leaking shale gas wells and induced earthquakes, and in some areas a population increasingly turning against the industry. The technology of horizontal drilling and hydraulic fracturing that was developed in the United States is now being tried outside the United States, including in Europe, Argentina, and China. There are clear reasons why shale gas might be attractive to Europe. It may offer security of energy supply to some countries particularly dependent on Russian gas, it could stimulate growth and jobs, and it could supply a cleaner fuel than coal in power stations. However, prospective shale often underlies areas of high population density in Europe, and moreover, populations that are unfamiliar with onshore gas operations. The main challenge in Europe therefore is not mainly technological but for the industry to achieve a “social license” and for Government and regulations to be manifestly protecting the public and property.

A study of the annual performance of bifacial photovoltaic modules in the case of vertical facade integration

Scipedia content — Thu, 01 Jun 2017 14:54:18 +0200

Despite the apparent benefits of bifacial modules, their application still suffers from a lack of visibility on the performance gain that they can actually provide. In this work, we consider the specific application of vertically oriented bifacial modules, notably for facade integration. We have developed a methodology to evaluate the annual electrical performance of bifacial modules based on three tools. First, a double illumination characterization setup is used in a solar simulator for comparing module architectures. Then, a reduced scale outdoor test bench allows us to evaluate bifacial module performance in a variety of configurations. Finally, a ray-tracing model validated with short-term outdoor data leads to the determination of the annual performance gain. This methodology allowed us to find optimal performance according to the most important parameters of application and module. Specifically, a module architecture using half-cut cells, a parallel cell interconnection, and textured glasses have been analyzed with respect to their influence on the resistive losses which increase in dual side illumination as well as to their influence on the effect of non- uniform and diffuse irradiance on the backside of the module. This work enabled us to give directions for innovative full-size module architectures.

Outdoor characterization and comparison of string and MLPE under clear and partially shaded conditions

Scipedia content — Thu, 01 Jun 2017 14:53:41 +0200

Building integrated and building attached photovoltaic (BIPV, BAPV) systems may suffer from lower performance than predicted as a result of unwanted partial shading. New system architectures have been proposed to optimize performance. The common approach of these new architectures is to track the maximum power point of every solar module individually. This paper demonstrates the effect of shading on energy yield by evaluating power level management on the module level compared to string level. Three independent PV systems were installed and extensively monitored in Eindhoven, a reference string inverter system, a power optimizer system and a micro inverter system. The DC and AC performance ratio (PR) of the systems have been analyzed for different weather types based on the clearness index. A pole shading covering 1–2% of the total system surface has been used to evaluate system performance under a specific type of partial shading. Module Level Power Electronics (MLPE) is capable of increasing the PR up to 35% under certain partial shading conditions. However, the string inverter system outperformed MLPE under unshaded operation conditions.

Ultrasound-assisted transesterification of refined and crude palm oils using heterogeneous palm oil mill fly ash supported calcium oxide catalyst

Scipedia content — Thu, 01 Jun 2017 14:52:59 +0200

Ultrasound-assisted transesterification of refined palm oil (RPO) and crude palm oil (CPO) to produce biodiesel using a palm oil mill fly ash supported calcium oxide (CaO) catalyst is studied in this work. The reaction time is significantly reduced from a maximum of 360 min under conventional mixing to just 30 min with the use of ultrasound. Under ultrasonic cavitation, the required catalyst loading and methanol to oil molar ratio to produce comparable yields and fatty acid methyl esters (FAME) conversions as conventional mixing are lower. For RPO, the ultrasound-assisted transesterification conditions of 60% ultrasonic amplitude, 30 min reaction time, 4 wt.% catalyst loading, and 9:1 methanol to oil molar ratio result in maximum biodiesel yield and FAME conversion of 85.23% and 97.02%, respectively. As for CPO, maximum biodiesel yield of 73.23% and FAME conversion of 97.04% are obtained under the same conditions with the exception of a methanol to oil molar ratio of 12:1. Key physicochemical properties of the produced biodiesels are found to be within the limits set by EN 14214 and ASTM D 6751. Catalyst reusability tests indicate that the catalyst can be used up to three consecutive cycles after regeneration using methanol washing followed by recalcination at 850°C for 2 h.

High moisture corn stover pelleting in a flat die pellet mill fitted with a 6 mm die: physical properties and specific energy consumption

Scipedia content — Thu, 01 Jun 2017 14:52:50 +0200

The quality and specific energy consumption (SEC) of the biomass pellets produced depend upon pelleting process conditions. The present study includes understanding the effect of feedstock moisture in the range of 28–38% (wet basis [w.b.]) and preheating in the range of 30–110°C at two die speeds of 40 and 60 Hz on the physical properties and SEC. A flat die pellet mill fitted with a 6 mm die was used in the present study. The physical properties of pellets such as moisture content, unit, bulk and tapped density, durability, and expansion ratio and SEC of the pelleting process are measured. The results indicate that the pellets produced have durability values in the range of 87–98%, and unit bulk and tapped density in the range of 670–1100, 375–575, and 420–620 kg/m3. Increasing the feedstock moisture content from 33% to 38% (w.b) decreased the unit, bulk and tapped density by about 30–40%. Increasing feedstock moisture content increased the expansion ratio and decreased the density values. A higher feedstock moisture content of 38% (w.b.) and higher preheating temperature of 110°C resulted in lower density and a higher expansion ratio, which can be attributed to flash off of moisture as the material extrudes out of the die. The SEC was in the range of 75–275 kWh/ton. Higher feedstock moisture content of 38% (w.b.) and a lower die speed of 40 Hz increased the SEC, whereas lower to medium preheating temperature (30–70°C), medium feedstock moisture content of 33% (w.b.), and a higher die speed of 60 Hz minimized the SEC to

Amorphous single-junction cells for vertical BIPV application with high bifaciality

Scipedia content — Thu, 01 Jun 2017 14:52:24 +0200

Solar cells used in building integration of photovoltaic cells (BIPV) are commonly made from crystalline wafer cells. This contribution investigates the challenges and benefits of using bifacial solar cells in vertical installations. We show that those cells get up to 13% more irradiance compared to optimum tilted south facing monofacial modules in Germany. The role of the n-layer in thin amorphous bifacial single-junction cells intended to be used as bifacial cells in BIPV applications is investigated. In contrast to the superstrate cell design, a transparent n-layer and back contact play a key role to achieve high bifaciality. We therefore increased the transparency of the n-layer by adding CO2, increasing the PH3 flow in the deposition gas and tested different thicknesses. With those measures, we reached a bifaciality of 98% for short-circuit current density and 99% for open-circuit voltage.

Unlocking the Full Potential of Hydropower

Alessandro Calvi — Wed, 15 May 2024 20:38:04 +0200

In this paper, a number of innovative technologies are presented that have the potential to improve the efficiency and utilization of
hydropower. These technologies include new turbine designs, improved efficiency, small hydro.