Scipedia: Documents published in 2017

Cover Image

Scipedia content — Thu, 01 Jun 2017 14:56:32 +0200

The cover image, by Allison Tolbert and Arthur J. Ragauskas, is based on the Review Advances in understanding the surface chemistry of lignocellulosic biomass via time-of-flight secondary ion mass spectrometry, DOI: 10.1002/ese3.144. The authors would like to acknowledge the following image contributors: Robert Davies (Renewable Bioproducts Institute, Georgia Tech) greatly assisted with the image formatting, Wellington Muchero and Jay Chen (Oak Ridge National Laboratory) and Bruce Arey (Environmental Molecular Science Laboratory) provided the Helium Ion Microscope image of Populus cell walls, and Chang Geun Yoo (Oak Ridge National Laboratory) assisted with the creative design.

Advances in understanding the surface chemistry of lignocellulosic biomass via time-of-flight secondary ion mass spectrometry

Scipedia content — Thu, 01 Jun 2017 14:56:21 +0200

Overcoming the natural recalcitrance of lignocellulosic biomass is necessary in order to efficiently convert biomass into biofuels or biomaterials and many times this requires some type of chemical pretreatment and/or biological treatment. While bulk chemical analysis is the traditional method of determining the impact a treatment has on biomass, the chemistry on the surface of the sample can differ from the bulk chemistry. Specifically, enzymes and microorganisms bind to the surface of the biomass and their efficiency could be greatly impacted by the chemistry of the surface. Therefore, it is important to study and understand the chemistry of the biomass at the surface. Time-of-flight secondary ion mass spectrometry (ToF-SIMS) is a powerful tool that can spectrally and spatially analyze the surface chemistry of a sample. This review discusses the advances in understanding lignocellulosic biomass surface chemistry using the ToF-SIMS by addressing the instrument parameters, biomass sample preparation, and characteristic lignocellulosic ion fragmentation peaks along with their typical location in the plant cell wall. The use of the ToF-SIMS in detecting chemical changes due to chemical pretreatments, microbial treatments, and physical or genetic modifications is discussed along with possible future applications of the instrument in lignocellulosic biomass studies.

In situ synchrotron-based X-ray powder diffraction and micro-Raman study of biomass and residue model compounds at hydrothermal conditions

Scipedia content — Thu, 01 Jun 2017 14:56:11 +0200

The applications of synchrotron X-ray powder diffraction (XRPD) and laser micro-Raman techniques in an examination of the dissolution, transformation, and gasification of pure cellulose and models for biomass residue under hydrothermal conditions in a diamond-anvil cell are reported. The results contribute to the measurement of in situ time-resolved profiles of biomass reactions, catalyst stability, and residue formation that occur in aqueous fluids at near- and supercritical conditions.

Fuzzy ARTMAP and GARCH-based hybrid model aided with wavelet transform for short-term electricity load forecasting

Scipedia content — Thu, 01 Jun 2017 14:56:01 +0200

With the evolution of the electricity market into a restructured smart version, load forecasting has emerged as an eminent research domain. Many forecasting models have been proposed by researchers for electricity price and load forecasting. This state of art introduces a load time series modeled with a hybrid technique culminating from the logical amalgamation of GARCH, a conventional hard computing method, Fuzzy ARTMAP, an artificial intelligence-based soft computing technique, and wavelet transform, for treating the load time series. The study investigates into the ability of the proposed hybrid model in tackling the electricity load time series forecasting problems. The work under this study also includes comparisons drawn among models which use either one or two of the mentioned techniques and the model proposed. Results certify the efficacy and effectiveness of the model over others.

Three-dimensional energetic and exergetic analysis of the injection orientation of DI diesel engine under different engine speeds

Scipedia content — Thu, 01 Jun 2017 14:55:48 +0200

Three-dimensional (3-D) computational code was implemented to solve conservation equations based on finite volume method as to simulate 1.8 L Ford diesel engine. Velocity and pressure of each computational cell is achieved by SIMPLE (semi-implicit method for pressure-linked equations) algorithm. For the exergetic aspect, the initial condition is set at 0.1 MPa and 300 K. The engine modeling is performed with 130 °, 140 °, and 150 ° with respect to x-axis under 1500 and 2500 rpm engine speeds. The results, however, indicate better air/fuel mixture (near stoichiometric equivalence ratio) for 130 ° of injection angle, albeit smaller spray droplets (lower sauter mean diameter) were introduced with 140 °. It is seen that higher soot and NOx mass fraction is attributed to 1500 rpm engine speed. The highest NOx and soot are exhausted at 130 ° and 150 ° of injection, respectively. Second law efficiency was calculated for different spray angle and engine speed schemes such that 36.62%, 30.2%, and 32.07% are associated with 130 °, 140 °, and 150 ° of injection angle under 1500 rpm, respectively. In terms of engine performance, that is, indicated mean effective pressure, indicated specific fuel consumption, and temperature, the best performance metrics are of 130 ° equal to 15.4 bar, 0.3856 kg/kW-h, and 2074.97 K under 1500 rpm, respectively. Instant irreversibility rate is the highest amount with peak value of 17.48 J/deg for 130 deg-1500 rpm, while 140 ° shows higher mean irreversibility rate over crank angle (CA) period.

A wavelet-nearest neighbor model for short-term load forecasting

Scipedia content — Thu, 01 Jun 2017 14:55:38 +0200

Load forecasts of short lead times ranging from an hour to a day ahead are essential for improving the economic efficiency and reliability of power systems. This paper proposes a hybrid model based on the wavelet transform (WT) and the weighted nearest neighbor (WNN) techniques to predict the day ahead electrical load. The WT is used to decompose the load series into deterministic series and fluctuation series that reflect the changing dynamics of data. The two subseries are then separately forecast using appropriately fitted WNN models. The final forecast is obtained by composing the predicted results of each subseries. The hourly electrical load of California and Spanish energy markets are taken as experimental data and the mean absolute percentage error (MAPE), Weekly MAPE (WMAPE) and Monthly MAPE (MMAPE) are computed to evaluate the forecasting performance of the next-day load forecasts. The forecasting efficiency of the proposed model is evaluated using db2, db4, db5 and bior 3.1 wavelets. The results demonstrate the forecasting accuracy of the proposed hybrid model.

An overview of proactive wind turbine control

Scipedia content — Thu, 01 Jun 2017 14:55:16 +0200

Recent achievements in the proactive turbine control, based on the upwind speed measurements, are described in a unified framework (as an extension of the tutorial [1]), that in turn represents a systematic view of the control activity carried out within the Swedish Wind Power Technology Center (SWPTC). A new turbine control problem statement with constraints on blade loads is reviewed. This problem statement allows the design of a new class of simultaneous speed and pitch control strategies based on the preview measurements and look-ahead calculations. A generation of a piecewise constant desired pitch angle profile which is calculated using the turbine load prediction is reviewed in this article as one of the most promising approaches. This in turn allows the reduction of the pitch actuation and the design of the collective pitch control strategy with the maximum possible actuation rate. Two turbine speed control strategies based on one-mass and two-mass models of the drivetrain are also described in this article. The strategies are compared to the existing drivetrain controller. Moreover, postprocessing technique that can be used for estimation of the turbine parameters with improved performance is also discussed. Postprocessing-based estimation of the turbine inertia moment is given as an example. All the results are illustrated by simulations with a wind speed record from the Hönö turbine, located outside of Gothenburg, Sweden.

Blade root moment sensor failure detection based on multibeam LIDAR for fault-tolerant individual pitch control of wind turbines

Scipedia content — Thu, 01 Jun 2017 14:55:04 +0200

Detection of blade root moment sensor failures is an important problem for fault-tolerant individual pitch control, which plays a key role in reduction of uneven blade loads of large wind turbines. A new method for detection of blade root moment sensor failures which is based on variations induced by a vertical wind shear is described in this paper. The detection is associated with monitoring of statistical properties of the difference between amplitudes of the first harmonic of the blade load, which is calculated in two different ways. The first method is based on processing of the load sensor signal, which contains a number of harmonics. The first harmonic is recovered via least squares estimation of the blade load signal with harmonic regressor and strictly diagonally dominant (SDD) information matrix. The second method is a model-based method of estimation of the first harmonic, which relies on the blade load model and upwind speed measurements provided by multibeam Light Detection and Ranging (LIDAR). This is a new application for future LIDAR-enabled wind turbine technologies. Moreover, adaptation of the load model in a uniform wind field is proposed. This adaptation improves accuracy of the load estimation and hence the performance of the blade load sensor failure detection method.

Shale gas in North America and Europe

Scipedia content — Thu, 01 Jun 2017 14:54:57 +0200

According to the U.S. Energy Information Administration, shale gas will provide half of the United States’ domestic gas by 2035. The United States has already moved from being one of the worlds largest importers of gas to being self-sufficient in less than a decade, bringing hundreds of thousands of jobs and attracting back companies that long ago left America in search of cheap manufacturing costs. But the increase in shale gas extraction has also had an environmental cost. There is clear scientific evidence of leaking shale gas wells and induced earthquakes, and in some areas a population increasingly turning against the industry. The technology of horizontal drilling and hydraulic fracturing that was developed in the United States is now being tried outside the United States, including in Europe, Argentina, and China. There are clear reasons why shale gas might be attractive to Europe. It may offer security of energy supply to some countries particularly dependent on Russian gas, it could stimulate growth and jobs, and it could supply a cleaner fuel than coal in power stations. However, prospective shale often underlies areas of high population density in Europe, and moreover, populations that are unfamiliar with onshore gas operations. The main challenge in Europe therefore is not mainly technological but for the industry to achieve a “social license” and for Government and regulations to be manifestly protecting the public and property.

Investigating residual trapping in CO2 storage in saline aquifers – application of a 2D glass model, and image analysis

Scipedia content — Thu, 01 Jun 2017 14:54:37 +0200

Two-dimensional glass model experiments are used to investigate the residual trapping mechanism of CO2 stored in saline aquifers. For this purpose, two proxy fluids are chosen to simulate the CO2-brine behavior under reservoir conditions. The first set of experiments is carried out by flooding n-heptane in a mixture of glycerol and water inside a glass bead porous media. Fluids and porous materials are designed so that the dimensionless groups are in the range of real storage sites. Another set of proxy fluid consists of dodecane and a different mixture of glycerol and water, representing the second wettability condition for the system. The size of the glass beads chosen was fine (70–110 μm) in order to investigate residual trapping phenomena. For each set, after complete drainage process, an imbibition process is performed and in each time step, images are taken from the phenomena. The images are processed using a red, green, blue (RGB) color concept using a Matlab code that was developed for this study. By using this process, it is possible to measure the residual trapping of CO2 proxy fluid for each test and to determine the saturation profile in the model. Tests are carried out at various imbibition and drainage rates to study the effect of the rate on the results. Fine-scale numerical simulation models are constructed for comparison with experimental results. Good agreement is obtained between the simulation results and the image processing estimations, as well as the readings from the material balances during the experiments. This study could provide a framework for modeling different reservoir conditions for residual trapping mechanism and the impact of different parameters in future studies.

A study of the annual performance of bifacial photovoltaic modules in the case of vertical facade integration

Scipedia content — Thu, 01 Jun 2017 14:54:18 +0200

Despite the apparent benefits of bifacial modules, their application still suffers from a lack of visibility on the performance gain that they can actually provide. In this work, we consider the specific application of vertically oriented bifacial modules, notably for facade integration. We have developed a methodology to evaluate the annual electrical performance of bifacial modules based on three tools. First, a double illumination characterization setup is used in a solar simulator for comparing module architectures. Then, a reduced scale outdoor test bench allows us to evaluate bifacial module performance in a variety of configurations. Finally, a ray-tracing model validated with short-term outdoor data leads to the determination of the annual performance gain. This methodology allowed us to find optimal performance according to the most important parameters of application and module. Specifically, a module architecture using half-cut cells, a parallel cell interconnection, and textured glasses have been analyzed with respect to their influence on the resistive losses which increase in dual side illumination as well as to their influence on the effect of non- uniform and diffuse irradiance on the backside of the module. This work enabled us to give directions for innovative full-size module architectures.

Practical evaluation of organic polymer thermoelectrics by large-area R2R processing on flexible substrates

Scipedia content — Thu, 01 Jun 2017 14:53:59 +0200

Here, we present a process based on roll-to-roll (R2R) technology which allows for very fast processing of polymer thermoelectric (TE) devices and we furthermore demonstrate a simplified but more efficient way of serially connecting these devices by means of R2R thin-film processing. The new device architecture makes it possible to use only one TE material (opposed to two materials which are employed in well-known Peltier elements), and a total of 18, 000 serially connected junctions were prepared by flexoprinting of silver electrodes and by rotary screen printing of poly(3, 4-ethylenedioxythiophene) (PEDOT):polystyrene sulfonate (PSS) as the TE material. Testing of devices revealed that the new architecture clearly showed to be functioning as expected, but also pointed toward challenges for thin-film TE development which is the influence of the substrate thickness on the thermal gradient over a device and the currently low performance available. A life-cycle assessment (LCA) was carried out in order to evaluate the sustainability of the new architecture and to estimate the requirements for development of a successful technology.

Study of demagnetization risk for a 12 kW direct driven permanent magnet synchronous generator for wind power

Scipedia content — Thu, 01 Jun 2017 14:53:50 +0200

One of the main aspects when designing a permanent magnet (PM) generator is to choose suitable PMs, both in terms of achieving the required flux in the generator but also of withstanding high demagnetizing fields, that is, having sufficiently high coercivity. If the coercivity is too low, the magnets are at risk of demagnetizing, fully or partially, at the event of a short circuit and/or an increase in temperature. This study aims to determine the risk of demagnetization for a 12 kW direct driven permanent magnet synchronous generator. Furthermore, as the prices on PMs have increased drastically the last few years the possibility to use smaller and/or cheaper PMs of different grades has been investigated. A new proprietary finite element method (FEM) model has been developed, which is also presented. The study is based on simulations from this FEM model and is focused on NdFeB magnets. Results show that the reference magnet can withstand a two-phase short circuit at both the temperatures tested and in both geometries. The use of cheaper magnets, smaller air gap and in the event of a two-phase short circuit often results in partial irreversible demagnetization. However, magnets with lower coercivity are easier demagnetized.

Outdoor characterization and comparison of string and MLPE under clear and partially shaded conditions

Scipedia content — Thu, 01 Jun 2017 14:53:41 +0200

Building integrated and building attached photovoltaic (BIPV, BAPV) systems may suffer from lower performance than predicted as a result of unwanted partial shading. New system architectures have been proposed to optimize performance. The common approach of these new architectures is to track the maximum power point of every solar module individually. This paper demonstrates the effect of shading on energy yield by evaluating power level management on the module level compared to string level. Three independent PV systems were installed and extensively monitored in Eindhoven, a reference string inverter system, a power optimizer system and a micro inverter system. The DC and AC performance ratio (PR) of the systems have been analyzed for different weather types based on the clearness index. A pole shading covering 1–2% of the total system surface has been used to evaluate system performance under a specific type of partial shading. Module Level Power Electronics (MLPE) is capable of increasing the PR up to 35% under certain partial shading conditions. However, the string inverter system outperformed MLPE under unshaded operation conditions.

Why the molten salt fast reactor (MSFR) is the “best” Gen IV reactor

Scipedia content — Thu, 01 Jun 2017 14:53:24 +0200

A simultaneously “nuclear”, permanent, and in-time solution to mankinds energy-related problems would require the relatively rapid manufacture of 10, 000–30, 000 genuinely sustainable, full-sized (~1 GWe) reactors. This “nuclear renaissance” would have to be implemented with breeder reactors because todays commercial nuclear fuel cycle is unsustainable and based upon a fuel (235U) that is intrinsically expensive and politically problematic. The purpose of this paper is to point out why a simple/cheap “minimal reprocessing” implementation of the European Unions (EUs) molten salt fast reactor (MSFR) concept represents the most promising way to implement that technical fix: Its primary drawback is that it would require virtually everyone currently involved with managing, researching, implementing, regulating, or “helping” the USAs nuclear power industry to embrace a massive paradigm shift.

Conducting polymer-based flexible supercapacitor

Scipedia content — Thu, 01 Jun 2017 14:53:12 +0200

Flexible supercapacitors, a state-of-the-art material, have emerged with the potential to enable major advances in for cutting-edge electronic applications. Flexible supercapacitors are governed by the fundamentals standard for the conventional capacitors but provide high flexibility, high charge storage and low resistance of electro active materials to achieve high capacitance performance. Conducting polymers (CPs) are among the most potential pseudocapacitor materials for the foundation of flexible supercapacitors, motivating the existing energy storage devices toward the future advanced flexible electronic applications due to their high redox active-specific capacitance and inherent elastic polymeric nature. This review focuses on different types of CPs-based supercapacitor, the relevant fabrication methods and designing concepts. It describes recent developments and remaining challenges in this field, and its impact on the future direction of flexible supercapacitor materials and relevant device fabrications.

Ultrasound-assisted transesterification of refined and crude palm oils using heterogeneous palm oil mill fly ash supported calcium oxide catalyst

Scipedia content — Thu, 01 Jun 2017 14:52:59 +0200

Ultrasound-assisted transesterification of refined palm oil (RPO) and crude palm oil (CPO) to produce biodiesel using a palm oil mill fly ash supported calcium oxide (CaO) catalyst is studied in this work. The reaction time is significantly reduced from a maximum of 360 min under conventional mixing to just 30 min with the use of ultrasound. Under ultrasonic cavitation, the required catalyst loading and methanol to oil molar ratio to produce comparable yields and fatty acid methyl esters (FAME) conversions as conventional mixing are lower. For RPO, the ultrasound-assisted transesterification conditions of 60% ultrasonic amplitude, 30 min reaction time, 4 wt.% catalyst loading, and 9:1 methanol to oil molar ratio result in maximum biodiesel yield and FAME conversion of 85.23% and 97.02%, respectively. As for CPO, maximum biodiesel yield of 73.23% and FAME conversion of 97.04% are obtained under the same conditions with the exception of a methanol to oil molar ratio of 12:1. Key physicochemical properties of the produced biodiesels are found to be within the limits set by EN 14214 and ASTM D 6751. Catalyst reusability tests indicate that the catalyst can be used up to three consecutive cycles after regeneration using methanol washing followed by recalcination at 850°C for 2 h.

High moisture corn stover pelleting in a flat die pellet mill fitted with a 6 mm die: physical properties and specific energy consumption

Scipedia content — Thu, 01 Jun 2017 14:52:50 +0200

The quality and specific energy consumption (SEC) of the biomass pellets produced depend upon pelleting process conditions. The present study includes understanding the effect of feedstock moisture in the range of 28–38% (wet basis [w.b.]) and preheating in the range of 30–110°C at two die speeds of 40 and 60 Hz on the physical properties and SEC. A flat die pellet mill fitted with a 6 mm die was used in the present study. The physical properties of pellets such as moisture content, unit, bulk and tapped density, durability, and expansion ratio and SEC of the pelleting process are measured. The results indicate that the pellets produced have durability values in the range of 87–98%, and unit bulk and tapped density in the range of 670–1100, 375–575, and 420–620 kg/m3. Increasing the feedstock moisture content from 33% to 38% (w.b) decreased the unit, bulk and tapped density by about 30–40%. Increasing feedstock moisture content increased the expansion ratio and decreased the density values. A higher feedstock moisture content of 38% (w.b.) and higher preheating temperature of 110°C resulted in lower density and a higher expansion ratio, which can be attributed to flash off of moisture as the material extrudes out of the die. The SEC was in the range of 75–275 kWh/ton. Higher feedstock moisture content of 38% (w.b.) and a lower die speed of 40 Hz increased the SEC, whereas lower to medium preheating temperature (30–70°C), medium feedstock moisture content of 33% (w.b.), and a higher die speed of 60 Hz minimized the SEC to

Pilot-scale processing with alkaline pulping and enzymatic saccharification for bioethanol production from rice straw

Scipedia content — Thu, 01 Jun 2017 14:52:42 +0200

We examined pilot-scale bioethanol production from rice straw using sodium carbonate pulping as the alkaline pulping method and enzymatic saccharification. The yield of prewashed rice straw after the crushing and prewashing stage decreased with an increase in the input in rice straw. The pulp yield after alkaline cooking was 66–68% at kappa number ranging from 32 to 36, which was comparatively higher than the laboratory-scale study. The yield of enzymatic saccharized glucose was decreased with the increase in washed pulp and its saccharification rate was approximately 20%. We successfully produced approximately 100 liters of 95% ethanol from 1000 Bone-Dry kg (BDkg) rice straw. The results of our pilot-scale study indicated that the relationship between resource input and product yield for each operation exhibited exponential or logarithmic curves, rather than linear decreases or increases, which could suggest a high-cost structure for bioethanol production when the resource input is larger. However, we established an optimum quantity of resource input, approximately 2000–3000 BDkg in our pilot-scale study, for higher efficiencies.

Nuclear fusion as a massive, clean, and inexhaustible energy source for the second half of the century: brief history, status, and perspective

Scipedia content — Thu, 01 Jun 2017 14:52:35 +0200

Fusion energy, based on the use of broadly available inexhaustible resources as lithium and deuterium and with minimal impact to the environment, aims at a change in the energy supply paradigm: instead of its current dependence on natural resources and environmental impact, energy would become a technology-dependent resource with unlimited adaptive availability and whose unit cost should decrease as technology progresses. This article intends to give a picture of where fusion research stands today and the perspectives: the achievements, the difficulties, the current status, marked by the construction of the ITER experiment which will demonstrate the scientific feasibility of fusion power, and the perspectives toward the first demonstration power plant, DEMO, which, according to the European Roadmap, could start the construction shortly after the full power experiments in ITER (

Amorphous single-junction cells for vertical BIPV application with high bifaciality

Scipedia content — Thu, 01 Jun 2017 14:52:24 +0200

Solar cells used in building integration of photovoltaic cells (BIPV) are commonly made from crystalline wafer cells. This contribution investigates the challenges and benefits of using bifacial solar cells in vertical installations. We show that those cells get up to 13% more irradiance compared to optimum tilted south facing monofacial modules in Germany. The role of the n-layer in thin amorphous bifacial single-junction cells intended to be used as bifacial cells in BIPV applications is investigated. In contrast to the superstrate cell design, a transparent n-layer and back contact play a key role to achieve high bifaciality. We therefore increased the transparency of the n-layer by adding CO2, increasing the PH3 flow in the deposition gas and tested different thicknesses. With those measures, we reached a bifaciality of 98% for short-circuit current density and 99% for open-circuit voltage.

Degradation of silicon wafers at high temperatures for epitaxial deposition

Scipedia content — Thu, 01 Jun 2017 14:52:11 +0200

The material quality degradation of silicon wafers by metal impurities, various crystal defects as well as light and thermally induced mechanisms is very important for the solar cell performance and has been investigated by various groups. In this paper, the material degradation during epitaxial deposition at high temperatures above 1100°C will be discussed. Annealing experiments in hydrogen atmosphere are done with the laboratory rapid thermal chemical vapor deposition reactor to mimic the thermal process conditions for epitaxial growth of silicon from the gas phase. A general investigation of crystallographic and electronic properties of n- and p-type silicon wafers has been done between 950°C and 1150°C. A detailed sensitivity analysis of process parameters like cooling ramp, peak temperature, duration, and ambient gasses has been conducted. The degradation mechanism by metal impurities has been investigated by using silicon wafers with different diffusion barriers. Besides effective minority carrier lifetime, measurements by quasi steady state photo conductance, etch pit density, Raman spectroscopy, X-ray diffraction, and Fourier transform infrared spectroscopy measurements have been done. The presented results have been used to improve the deposition process of epitaxial thin-film solar cells, the production of silicon foils with a thickness

Combined solar heat and power with microgrid storage and layered smartgrid control toward supplying off-grid rural villages

Scipedia content — Thu, 01 Jun 2017 14:52:01 +0200

A project has been initiated in South Africa to design, model, build, and evaluate an easy to install solar fueled combined heat and power (micro-CHP) system to supply off-grid rural villages and eco-estate communities. This study describes the design of a model that offers a combined 3 kW peak electrical, 12 kW peak thermal, stand-alone solar power technology solution with microgrid storage to deliver power, and heat when the sun is shining and after sunset (at night time). The CHP demand side management system manages power and heat distribution to individual households in a small rural village based on a proposed smart microgrid technology solution. The solution aims to balance the heat/power demand side requirements based on digital feedback on heat/power utilization patterns and user demand. Aspects of the micro-CHP system microgrid control are discussed while a modular smartgrid solution is selected for smart microgrid applications.

Next generation biorefineries will solve the food, biofuels, and environmental trilemma in the energy–food–water nexus

Scipedia content — Thu, 01 Jun 2017 14:51:55 +0200

The future roles of biomass and carbohydrate for meeting needs of food/feed, renewable materials, and transportation fuels (biofuels) remain controversial due to numerous issues, such as increasing food and feed needs, constraints of natural resources (land, water, phosphate, biomass, etc.), and limitations of natural photosynthesis, as well as competing energy conversion pathways and technologies. The goal of this opinion article is to clarify the future roles of biomass and biorefineries using quantitative data other than adjective words. In most scenarios, human beings could have enough biomass resource from plant photosynthesis for meeting the three goals at the same time: feeding 9 billion people, providing renewable materials, and producing transportation biofuels that could replace nearly all fossil fuel-based liquid fuels used in the land transportation in 2050. Land transport means will pass through transitions from internal combustion engines plus liquid fuels, to hybrid systems, to hydrogen fuel cell vehicles (FCVs), while battery electric vehicles (BEVs) could play a minor role. Next generation biorefineries based on artificial photosynthesis featuring ultra-high energy efficiency and low-water consumption could produce a large amount of carbohydrate and/or other biocommodities from hydrogen/electricity and CO2. In conclusion, it is time to develop next generation biorefineries, which will efficiently utilize nonfood biomass for the coproduction of multiple products from biofuels, biochemicals, to food/feed, and even store electricity/hydrogen by fixing CO2 to carbon-containing chemicals and biofuels. Next generation biorefineries will address the food, biofuels, and environment trilemma at the same time.

Cost modeling of lithium-ion battery cells for automotive applications

Scipedia content — Thu, 01 Jun 2017 14:51:46 +0200

The purpose of this study was to highlight the technical and economic issues arising in lithium-ion cells for automotive applications, and to indicate some potential solutions to lower the cost. This topic has already been the subject of some studies, but, although of primary importance, the role on cost of a cell design parameter, the electrode coating thickness, has rarely been described. This study intends to explore particularly the influence of this parameter. To do so, the cost of cells with four positive electrode materials (NMC, NCA, LFP, and LMO), and the same negative electrode material are compared at several electrode thickness. The cost of these cells is computed using an innovative model and varies between 230 and 400 $ per kWh. With the assumptions used, it appears that the potential savings resulting from doubling the electrode coating thickness from 50 to 100 μm at a given porosity represent roughly 25% of the cell cost. The electrode coating thickness emerges as an essential parameter for an unbiased cells cost comparison. This article gives a view of the current lithium-ion cells costs, and provides guidelines to lower cells cost.

Low-grade heat recycling for system synergies between waste heat and food production, a case study at the European Spallation Source

Scipedia content — Thu, 01 Jun 2017 14:51:40 +0200

At present food production depends almost exclusively on direct use of stored energy sources, may perhaps they be nuclear-, petroleum-, or biobased. Arable land, artificial fertilizers, and fresh water resources are the base for our present food systems, but are limited. At the same time, energy resources in the form of waste heat are available in ample quantities. The European Spallation Source (ESS) will require approximately 270 GWh of power per year to operate, power that ultimately is converted to heat. This multidisciplinary case study details an alternative food production cooling chain, using low-grade surplus heat, and involving fermentation, aquaculture, nutrient recapture, and greenhouse horticulture including both use of low-grade surplus heat and recycling of societys organic waste that is converted to animal feed and fertilizer. The study indicates that by combining the use of surplus energy with harvest of societys organic side flows, for example, food waste and aquatic-based cash crops, sustainable food systems are possible at a level of significance also for global food security. The effects of the proposed heat reuse model are discussed in a system perspective and in the context of the UNSCD indicator framework. The potential sustainability benefits of such an effort are shown to be substantial and multifaceted.

Assessment of the minimum value of photovoltaic electricity in Italy

Scipedia content — Thu, 01 Jun 2017 14:51:29 +0200

We investigate the value of solar photovoltaic (PV) power in the Italian wholesale electricity market (IPEX). A model is developed and applied to simulate and predict the monthly average electricity prices in peak hours, as well as to simulate scenarios without PV generation. The computed merit-order effect of the PV generation in Italy, around −2.9 €/MWh per each additional GWh of PV production, as well as the greater −4.5 €/MWh absolute value evaluated under the hypothesis of stationary electricity demand, are in line with the upper values found in related studies of near mature renewable energy markets. A strong relationship of the value of PV electricity in the IPEX with the electricity demand is clearly evident, leading to important policy implications in terms of possible actions on the granted subsidies, electrification of energy end use, and promotion of specific PV technologies. The anomalous temporal behavior of the IPEX, shown by high off-peak electricity prices that followed the installation of Italys large PV park, partly offsets the beneficial effect of PV generation.

Solar power in Quebec: a unique potential soon to be fulfilled

Scipedia content — Thu, 01 Jun 2017 14:51:21 +0200

Quebecs large solar power potential markedly contrasts with its poor achievements in using solar energy in this large and wealthy region of the world. Reviewing recent developments and putting discussion in the socioeconomic context, we provide arguments that justify our viewpoint that solar energy will soon be a relevant source of power in this Province of Canada. The rapid fall in price of both main solar power technologies, photovoltaics, and solar thermal, along with significant levels of insolation and the pronounced environmental awareness of Quebecs population support the conclusions of this study.

Thermoeconomic and thermoenvironomic modeling and analysis of selected gas turbine power plants in Nigeria

Scipedia content — Thu, 01 Jun 2017 14:51:04 +0200

This study presents comprehensive thermoeconomic and thermoenvironomic modeling and analysis of selected gas turbine power plants in Nigeria using the first and second laws of thermodynamics (exergy) concept. Exergetic analysis was conducted using operating data obtained from the power plants to determine the exergy destruction and exergy efficiency of each major component of the gas turbine in each power plant. The results of the study showed that the combustion chamber (CC) is the most exergy destructive component compared to other cycle components. The percentage of exergy destruction in CC varies between 86.05% and 94.6%. By increasing the gas turbine inlet temperature (GTIT), the exergy destruction of this component can be reduced. The total exergy improvement potential of the selected plants varies from 54.04 to 159.88 MW. The component with the highest exergy improvement potential is the CC, which has the value that varies from 30.21 to 88.86 MW. Thermoeconomic analysis showed that the cost of exergy destruction is high in the CC, and an increase in the GTIT effectively decreases this cost. The exergy costing analysis revealed that the unit cost of electricity produced in the plants ranged from cents 1.99/kWh (N3.16/kWh) to cents 5.65 /kWh (N8.98/kWh). Thermoenvironomic analysis showed that the CO2 emissions varied between 100.18 and 408.78 kg CO2/MWh, while cost rate of environmental impact varied from 40.18 $/h (6, 388.62 N/h) to 276.97 $/h (44, 038. 23 N/h). The results further showed that CO2 emissions and cost of environmental impact decrease with increasing GTIT. The sustainability index increase with increasing GTIT. Finally, this study will assist efforts to understand the thermodynamic losses in the gas turbine cycle, and to improve efficiency as well as provide future recommendations for better performance, sustainability, and lessening environmental impact of power plant.

Assessment of performance indices of selected gas turbine power plants in Nigeria

Scipedia content — Thu, 01 Jun 2017 14:50:49 +0200

In this study, performance assessment of selected gas turbine power plants in Nigeria was evaluated using performance indices. The results of the study showed that for the period under review (2006–2010), the percentage shortfalls from the target energy in the selected power plants range from 26.33% to 86.61% as against the acceptable value of 5–10%. The capacity factor of the selected power plants varies from 16.88% to 73.67% as against the international value of 50–80%. The plant use factor varies from 45.89% to 97.03% and the utilization factor varies from 6.31% to 93.074% as against the international best practice of over 95%. From this result, it can be concluded that the generating units were underutilized. This is due to inadequate routine maintenance and equipment fault development. The analyses of reliability indicators revealed that the mean time between failures varies from 5.42 to 378.44 h, the mean time to repair varies from 18.3 to 153.88 h and the plant availability varies from 12.86% to 91.31% as against the Institute of Electrical and Electronics Engineers recommended standard of 99.9%. Evaluation of operating figures of the selected power plants revealed that starting reliability (SR) and operating reliability vary from 71.95% to 93.9% and 5.33% to 55%, respectively. The SR of the selected power plants is low in value compared with standard value of 99.9%. The statistical analysis carried out on plant availability revealed that at 95% confidence level, there is a significant difference in availability of the selected power plants. This indicates differences in their systems installation, operation and maintenance. The performance indicator developed to evaluate the performance indices for the selected stations can also be applicable to other power stations in Nigeria and elsewhere. Measures to improve the performance indices of the plants have been suggested in this paper.

Techno-economic analysis of hybrid PV–diesel–battery and PV–wind–diesel–battery power systems for mobile BTS: the way forward for rural development

Scipedia content — Thu, 01 Jun 2017 14:50:38 +0200

In recent times, hybrid renewable energy systems are increasingly being utilized to provide electricity in remote areas especially where the grid extension is considered too expensive. This study presents the results of techno-economic analysis of hybrid system comprising of solar and wind energy for powering a specific remote mobile base transceiver station (BTS) in Nigeria. All the necessary modeling, simulation, and techno-economic evaluation are carried out using the assessment software package HOMER (Hybrid Optimization Model for Electric Renewable). Two best optimal system configurations namely PV–diesel–battery and PV–wind–diesel–battery systems are compared with the conventional stand-alone diesel generator (DG) system. Findings indicated that PV array (10 kW) – DG (5.5 kW) – battery (64 units Trojan L16P) is the most economically viable option with the total net present cost of $69, 811 and per unit cost of electricity of $0.409. The sensitivity analysis is also carried out to find the effects of probable variation in solar radiation, wind speed, and diesel price in the optimal system configurations. Finally, the environmental benefit of hybrid systems over the conventional stand-alone diesel system is described. The obtained results show that the hybrid PV–diesel–battery system provides a reduction in CO2 emissions of about 16.4 tons per year as compared to the stand-alone DG system.

A simulation study of a bioethanol-solar-reforming system for proton-exchange membrane fuel cell home cogeneration system

Scipedia content — Thu, 01 Jun 2017 14:50:24 +0200

The energy supply characteristic of a proton-exchange membrane fuel cell for houses is strongly influenced in a hydrogen supply unit. Therefore, a bioethanol reforming system (FBSR) with a sunlight heat source is developed as a potential fuel supply system for distributed fuel cells. However, the temperature distribution of a catalyst layer in the reactor is not stable under conditions of unstable solar radiation and unstable outside air temperature, as a result, it is thought that the inversion ratio (the percentage of hydrogen obtained from ethanol) of a reforming reaction will decrease. In this paper, heat transmission analysis was used in the catalyst layer of the reformer of FBSR, and the fundamental performance of FBSR was investigated. Fluctuations of the solar insolation over a short period of time affect the hydrogen-generating rate of FBSR. Moreover, the amount of hydrogen production of FBSR was simulated using meteorological data from a day in March and a day in August in a cold region (Sapporo in Japan). In this research, the relation between the collected area of a solar collector and the energy supply to an individual house was obtained.

Testing of the Katrix rotary lobe expander for distributed concentrating solar combined heat and power systems

Scipedia content — Thu, 01 Jun 2017 14:50:12 +0200

In this article, we present performance results and analysis of a novel rotary lobe expander device. This is part of a larger research effort into the analysis and design of a small-scale solar system that would compete with available distributed technologies for heat and electricity generation. To choose an appropriate working fluid and components for a distributed concentrating solar combined heat and power (DCS-CHP) system, we compared many different working fluids, collectors, and expander choices. Of the expanders analyzed, including piston expanders, radial inflow turbines, Tesla turbines, screw expanders, and scroll expanders, the rotary lobe expander shows the greatest promise in small-scale power applications due to its high efficiency in expanding fluids over large pressure ratios and its low cost to manufacture. This article focuses on testing of a prototype small-scale expander that was chosen because, to date, no suitable commercial product of less than 10 kW has been found for this application. Initial testing was completed with air to get results that should be indicative of future testing with steam. The test system consists of a compressed air expander (a prototype designed by Katrix, Inc. of Australia) connected to an induction motor driven by a variable frequency drive (VFD) that enables expander testing at varying shaft speeds. Results of the expander testing are reported isentropic efficiencies of 22–25%, thermomechanical efficiencies of 80–95%, and pressure ratios of 6–11 at the tested speeds. Despite mixed results from this particular expander, future refinements could lead to a new class of expanders with low cost and high performance for use in solar combined heat and power and waste-heat recovery.

Comparing oxidative and dilute acid wet explosion pretreatment of Cocksfoot grass at high dry matter concentration for cellulosic ethanol production

Scipedia content — Thu, 01 Jun 2017 14:50:01 +0200

The choice of a suitable pretreatment method and the adjustment of the pretreatment parameters for efficient conversion of biomass are crucial for a successful biorefinery concept. In this study, cocksfoot grass, a suitable lignocellulosic biomass with a potential for large-scale production was investigated for cellulosic ethanol production. The biomass raw materials were pretreated using wet explosion (WEx) at 25% dry matter concentration with addition of oxygen or dilute sulfuric acid. The enzymatic hydrolysis of cellulose was significantly improved after pretreatment. The highest conversion into cellulose monomeric C6 sugars was achieved for WEx condition AC-E (180°C, 15 min, and 0.2% sulfuric acid). For that condition, the highest ethanol yield of 197 g/kg DM (97% of theoretical maximum value) was achieved for SSF process by Saccharomyces cerevisiae. However, the highest concentration of hemicellulose C5 sugars was found for WEx pretreatment condition O2-A (160°C, 15 min, and 6 bar O2) which means that the highest potential ethanol yield was found at this moderate pretreatment condition with oxygen added. Increasing the pretreatment temperature to 180–190°C with addition of oxygen or dilute sulfuric acid significantly degrades the solubilized hemicellulose sugars and thus, achieved the highest formation of by-products.

Irradiance adjustment system developed for various types of solar cells and illumination conditions

Scipedia content — Thu, 01 Jun 2017 14:49:51 +0200

A new irradiance adjustment system for the light source named “Programmable Reference cell system for Irradiance adjustment by Spectral Measurement (PRISM)” has been developed for photovoltaics evaluation. It can be applied for various kinds of solar cells and illumination conditions without the preparation of conventional reference cells. This system consists of a device for absolute spectral responsivity measurements, that is, the spectral responsivity unit, and a device for irradiance adjustment of the light source, that is, the spectral reference cell. First, the short circuit current of the target solar cell (Iref) is calculated by convolution of the absolute spectral responsivity with the spectral irradiance under STC (AM1.5 G, 1 kW/m2, 25°C) as defined in IEC 60904-3. The spectral irradiance of the light source is then adjusted for I–V measurements so that the short-circuit current of the spectral reference cell (Ical), calculated by convolution of the absolute spectral responsivity with the spectral irradiance of the light source, agrees with Iref. The difference between Iref and the short circuit current, as determined at an internationally recognized test center under STC, was within ±2% for crystalline silicon solar cells and ±3% for organic solar cells. The difference between Ical and the short-circuit current measured under a solar simulator or LED in which the irradiance was adjusted by this system was within ±4% when the irradiance was higher than 4 W/m2.

The generation of power from a cement kiln waste gases: a case study of a plant in Kenya

Scipedia content — Thu, 01 Jun 2017 14:49:42 +0200

The cement production process is energy intensive both in terms of the thermal energy (firing the kiln, drying and De carbonation) and electrical energy for driving the numerous drives within the process line. The average specific power consumption of the case study plant was 111 kWh/ton of cement with an average peak demand of 9.7 MW. The high cost of electric power at 0.14 USD/kWh results in very high cost of production that significantly lowers the companys profit margin and limits its competitive advantage. The generation of electrical power from waste heat recovery would reduce the electricity power bill through partially substituting the power procured from the national grid. This research evaluated the potential that the plant has for generating electrical power from the hot waste gases vented into the atmosphere and it was found that the plant has the potential to generate 3.4 MWh of electrical power. This results to a net potential to generate 2.89 MWh of electrical power after factoring in the auxiliary power consumption by Waste heat recovery plant system at 15%. This ultimately gave a reduction of 33% in the electricity power bill of the case study plant. The paper recommends the installation of a steam rankine cycle for the power generating plant. In this work the authors designed the steam boilers for the waste heat recovery plant for conversion of thermal energy to electrical energy, selected a commercial steam turbine and evaluated its economic feasibility and established that the designed plant would have a simple payback period of 2.7 years.

The progressive routes for carbon capture and sequestration

Scipedia content — Thu, 01 Jun 2017 14:49:34 +0200

The global warming is directly related to the increased greenhouse gas emissions from both natural and anthropogenic origins. There has been a drastic rise in the concentration of CO2 and other greenhouse gases since the industrial revolution primarily due to the intensifying consumption of fossil fuels. With the need to reduce carbon emissions and mitigate global warming certain strategies relating to carbon capturing and sequestration are indispensable. This paper comprehensively describes several physicochemical, biological and geological routes for carbon capture and sequestration. The trend of the increase in greenhouse gases over the years is illustrated along with the global statistics for fossil fuels usage and biofuels production. The physicochemical carbon capturing technologies discussed include absorption, adsorption, membrane separation and cryogenic distillation. The algal and bacterial systems, dedicated energy crops and coalbed methanogenesis have been vividly explained as the biological routes for carbon sequestration. The geological carbon sequestering route centers on biochar application and oceanic carbon storage. A systematic survey has been made on the origin and impact of greenhouse gases along with the potential for sequestration based on some fast-track and long-term sequestration technologies.

Butanol and ethanol production from lignocellulosic feedstock: biomass pretreatment and bioconversion

Scipedia content — Thu, 01 Jun 2017 14:49:24 +0200

Lignocellulosic feedstock has tremendous potential to sustain the renewable production of biofuels such as ethanol and butanol. Although lignocellulosic biomass is a storehouse of energy in the form of cellulose and hemicellulose, yet lignin acts as a barrier against their hydrolysis. A dilute acid pretreatment disintegrates the biomass complex and allows cellulolytic enzymes to hydrolyze cellulose and hemicelluloses in releasing fermentable sugars. The current study investigates the effect of different H2SO4 doses (0–2.5%) on the three lignocellulosic feedstock material, especially pinewood, timothy grass, and wheat straw at 121°C for 1 h. Furthermore, the pretreated feedstock was subjected to enzymatic hydrolysis using cellulase, β-glucosidase, and xylanase at 45°C for 72 h. The biomass hydrolysates containing monomeric sugars (glucose and xylose) were fermented using Saccharomyces cerevisiae and Clostridium beijerinckii for ethanol and butanol production, respectively. A comparative evaluation for the concentrations of ethanol and butanol, residual sugars as well as byproducts such as acetone, acetate, and butyrate from biomass hydrolysates was performed. Pinewood hydrolysate revealed high ethanol (24.1 g/L) and butanol (11.6 g/L) concentrations due to greater sugar content. In contrast to ethanol fermentation by S. cerevisiae, butanol fermentation by C. beijerinckii demonstrated low butanol levels in the hydrolysates due to butanol toxicity toward clostridia.

Study of thermal behavior of deoiled karanja seed cake biomass: thermogravimetric analysis and pyrolysis kinetics

Scipedia content — Thu, 01 Jun 2017 14:49:14 +0200

Karanja is a medium sized evergreen tree which has minor economic importance in India. The nonedible seed kernel contains 27–30% oil that is used for biodiesel production, leaving the remaining nonedible seed cake as a waste product. The aim of the present work was to obtain kinetic parameters in relation to technological parameters in nonedible seed cake biomass pyrolysis conversion process to bio-oil and biochar. Effects of heating rate on karanja seed cake slow pyrolysis behavior and kinetic parameters were investigated at heating rates of 5, 10, and 20°C/min using thermogravimetric analysis (TGA). Thermogravimetric experiments showed the onset and offset temperatures of the devolatilization step shifted toward the high-temperature range, and the activation energy values increased with increasing heating rate. In the present study, isoconversional method was applied for the pyrolysis of karanja seed cake biomass by TGA and the activation energies (118–124 kJ/mol) and the pre-exponential factors obtained using progressive conversion. Proximate–ultimate analyses, energy value, surface structure, and Fourier transform infrared spectra of the biomass processed under conditions were reported. The pyrolysis resulted in upgradation of the energy value of seed cake biomass from 18.1 to 24.5 MJ/kg, importantly with high carbon and low oxygen contents. The approach represents a novel method for the upgrading of karanja seed cake that has significant commercial potential.

Postcombustion CO2 capture using N-(3-trimethoxysilylpropyl)diethylenetriamine-grafted solid adsorbent

Scipedia content — Thu, 01 Jun 2017 14:49:00 +0200

In this work, the performance of N-(3-trimethoxysilylpropyl)diethylenetriamine (DAEAPTS)-grafted mesoporous SBA-15 adsorbent for postcombustion carbon capture was studied. Wet grafting technique was adopted to functionalize SBA-15 surface. The adsorption of CO2 on the amine-grafted sorbent was measured by the thermogravimetric method over a CO2 partial pressure range of 0–90 kPa and a temperature range of 25–105°C under atmospheric pressure. The optimal amine loaded SBA-15 adsorbent containing 40 wt% DAEAPTS exhibited capture capacity up to 2.3 mmol/g under simulated gas conditions (88.2% CO2/N2) at 75°C. The CO2 adsorption–desorption kinetics of the grafted sorbents were found to be sufficiently fast in both dry and humid CO2 streams and it was observed that the grafted adsorbent achieved 75% of the total capacity in 5 min of adsorption time in dry 8.8% CO2/N2 and in less than 3.5 min in humid 8.8% CO2/N2. It was also observed that 95% of the total desorption occurred in less than 7 min at 150°C under pure N2. The grafted sorbents showed good reversibility and multicycle stability and the drop in capacity after 100 cycles in dry and humid 8.8% CO2/N2 streams was around 7.09% and 11.65%, respectively.

The remarkable impact of renewable energy generation in Sicily onto electricity price formation in Italy

Scipedia content — Thu, 01 Jun 2017 14:48:50 +0200

During the first half of 2015, for the first time, the zonal electricity price in Sicily decreased below than the national wholesale price in Italy. Showing the unique pattern of electricity consumption in Italys largest region at different time scales, we identify the effectiveness of the impact of renewable power generation on utility-scale in Sicily upon the whole of Italys electricity market. Increasing the electrification of the energy end uses, as it is happening despite prolonged reduction in electricity demand, will lead to further benefits for power consumers throughout the whole country.

The great solar boom: a global perspective into the far reaching impact of an unexpected energy revolution

Scipedia content — Thu, 01 Jun 2017 14:48:38 +0200

This study offers a unified perspective into the unexpected solar energy photovoltaic revolution, and its far reaching impact onto both energy generation and electricity markets. Practically relevant aspects, such as those related to the value of solar PV electricity, land consumption, energy return on energy invested, reliability of the technology, the structure of the global PV industry, the cost of Li ion batteries and related market trends are clarified. We identify the main barriers to overcome for solar PV to expand beyond a niche market (say,

Coevaporated calcium-silver metal alloys as contact for highly transparent organic solar cells

Scipedia content — Thu, 01 Jun 2017 14:48:22 +0200

We present 10-nm thick metal alloys created by coevaporation of calcium and silver as transparent top electrode for inverted bulk heterojunction small-molecule organic solar cells (SMOSC). It is shown that such alloys exhibit sufficiently high conductivity to replace previously used thicker (>14 nm) pure Ag contacts. At the same time, Ca:Ag alloys have higher transmittance compared to pure Ag, which is desirable for semitransparent SMOSC where the light passes through the device and the metal contact. We find that a metal contact consisting of 1 nm Ag underlayer and 10 nm Ca:Ag of 1:1 mixing ratio (total Ag content by volume of 6 nm) on glass has an average transmittance in the visible range of 76% with a sheet resistance of 27.1 Ω/□, approaching the performance of ITO while being applied by a much gentler deposition method. Application of 10-nm thick alloys in semitransparent SMOSC lead to transmittance in the visible range Tvis of up to 49% and efficiency η of up to 2.3%, showing superior performance compared to devices with pure Ag top contacts.

Biodiesel from grease interceptor to gas tank

Scipedia content — Thu, 01 Jun 2017 14:48:15 +0200

The need for sustainable biofuels has initiated a global search for innovative technologies that can sustainably convert nonfood bioresources to liquid transportation fuels. While 2nd generation cellulosic ethanol has begun to address this challenge, other resources including yellow and brown grease are rapidly evolving commercial opportunities that are addressing regional biodiesel needs. This review examines the technical and environmental factors driving the collection of trap FOG (Fats, Oils, and Greases), its chemical composition and technologies currently available and future developments that facilitate the conversion of FOG into biodiesel.

Design, operation, and performance evaluation of a cable-drawn dual-axis solar tracker compared to a fixed-tilted system

Scipedia content — Thu, 01 Jun 2017 14:48:06 +0200

This article discusses the design, operation, and performance evaluation of a unique cable-operated 6.24 kWp commercial-size solar tracking system called iPV dual-axis tracker or iPV DAT with a position detector to gain the maximum power from the sunlight. Compared with other solar tracking systems, low cost, simplified hardware structure, and controlling algorithm are the advantages of this system. The operating method of the 6.24 kWp iPV DAT follow a simple pull and release of the steel cables connecting the corners of the PV module frame to the electric motors and directed by an electronic control system. The steel cables attached to the corners of the module frame also provide an extra stability in the event of high wind of up to 220 km/h. The accuracy of the tracking effect is managed by an astronomical algorithm that enables a full 360° azimuth rotation and altitude tilt of −40° to 40° (0 = horizontal). The controller algorithm also includes backtracking capability that allows optimization of ground cover ratio. Performance evaluation of the iPV DAT installed and operated in Taiwan for 12 months is compared with a fixed-tilt PV system. An average electricity gain of 30.1% and performance ratio of 93% are realized using iPV DAT.

Dynamic modeling of a small open Joule cycle reciprocating Ericsson engine: simulation results

Scipedia content — Thu, 01 Jun 2017 14:47:52 +0200

Externally heated Joule cycle reciprocating engines, also known as Ericsson engines, are particularly suitable for small-scale solar energy conversion and microcogeneration using biomass or gas effluents at high temperatures. These types of engine have been developed in the context of the current issue of climate change, combined with a progressive depletion of fossil fuels. A dynamic model of a 1.67 kW small open Joule cycle engine has been developed in order to study operational stability and behavioral control, especially during transient phases. Models are implemented on a Matlab/Simulink platform where simulations of the dynamics of engine start-up and steady conditions are carried out. The optimal settings of valves and the key engine parameters have also been determined. Simulation results reveal a rapid transient phase. Hot starting is achieved in about 5.3 sec and the system is stabilized, with a thermal efficiency of approximately 29%. The system responds well when subjected to selected perturbations.

An A-CAES pilot installation in the distribution system: A technical study for RES integration

Scipedia content — Thu, 01 Jun 2017 14:47:41 +0200

In the last decade in Europe, the power generated by Renewable Energy Sources (RES) has significantly increased. For the electric power system, the integration of a high amount of power generated by RES represents a big challenge. Energy Storage Systems (ESS) may help to solve problems related to the grid integration of RES. In this study, an analysis of the benefits that a planned and dedicated Adiabatic Compressed Air Energy Storage (A-CAES) system may provide to a distribution network with a high penetration of RES will be carried out. The A-CAES system, taken into account in this investigation, is based on the proposed German study so-called “ADELE project”. The technical benefits as well as the corresponding costs that A-CAES brings to the system which were analyzed using the load and RES generation time series for 2010 and 2020, and were based on technical data from a selected part of a German distribution power network, were evaluated and results of those broad investigations are presented in this study. The result of the investigations shows that the direct technical benefits are quite limited for the A-CAES technology as it exists today.

Systematic study of aqueous monoethanolamine-based CO2 capture process: model development and process improvement

Scipedia content — Thu, 01 Jun 2017 14:47:30 +0200

In this paper, we present improvements to postcombustion capture (PCC) processes based on aqueous monoethanolamine (MEA). First, a rigorous, rate-based model of the carbon dioxide (CO2) capture process from flue gas by aqueous MEA was developed using Aspen Plus, and validated against results from the PCC pilot plant trials located at the coal-fired Tarong power station in Queensland, Australia. The model satisfactorily predicted the comprehensive experimental results from CO2 absorption and CO2 stripping process. The model was then employed to guide the systematic study of the MEA-based CO2 capture process for the reduction in regeneration energy penalty through parameter optimization and process modification. Important process parameters such as MEA concentration, lean CO2 loading, lean temperature, and stripper pressure were optimized. The process modifications were investigated, which included the absorber intercooling, rich-split, and stripper interheating processes. The minimum regeneration energy obtained from the combined parameter optimization and process modification was 3.1 MJ/kg CO2. This study suggests that the combination of a validated rate-based model and process simulation can be used as an effective tool to guide sophisticated process plant, equipment design and process improvement.

Models and experiments for energy consumption and quality of green tea drying

Scipedia content — Thu, 01 Jun 2017 14:47:19 +0200

An experimental apparatus has been developed to evaluate the drying process of green tea leaves. Tea drying is an energy-intensive process which results in the removal of leaf moisture, it is essential to the quality of the final product. In order to more efficiently use process energy, a prototype drying system has been built and tested. The prototype incorporates a rotating perforated drum which helps speed the drying process. Experiments were carried out with multiple temperatures, airflow rates, and drum rotation rates, a subset of those results is shown here. In particular, the impact of airflow rate on the process was studied. It was found that as the airflow increased, the drying rate increased, as expected. However, the efficiency of energy use, which was quantified by the Specific Energy Consumption rate, varied considerably with flow. While higher flows led to faster drying, it resulted in a lower energy efficiency. Also, a two parameter predictive model was developed that was able to accurately match the moisture removal rates for a very wide range of flows. This predictive model, which is based on thermal-fluid fundamentals, can be used to extrapolate the presented results to cases which were not considered.

Steady-state and transient voltage stability analysis of a weak distribution system with a remote doubly fed induction generator-based wind farm

Scipedia content — Thu, 01 Jun 2017 14:47:08 +0200

In modern, stressed distribution system, voltage stability is a major concern from planning and operation perspectives. Remote wind farm connected to a weak distribution system through a long line could adversely affect the voltage stability of the respective distribution network. This paper investigates the transient and steady-state voltage issues of a distribution network with a distant doubly fed induction generator (DFIG)-based wind farm. Results show that a distant DFIG-based wind farm could improve the voltage stability of a distribution network with a large motor load in steady-state operating condition as well as following disturbances, like three-phase faults, sudden load tripping, and motor starting.

Various operating methods and parameters for SO2 electrolysis

Scipedia content — Thu, 01 Jun 2017 14:46:58 +0200

The application of PFSA-based proton exchange membranes was investigated for the production of hydrogen and sulfuric acid using a SO2-depolarized electrolyzer system. Parameters investigated included hot pressing pressure for the membrane electrode assembly (MEA) manufacturing, cell temperature, membrane thickness, catalyst loading, membrane type, and SO2 anode feed concentration. The effect of cell temperature, membrane thickness, and acid concentrations was also investigated when using a second method, where clean sulfuric acid as cathode and SO2 saturated sulfuric acid as anode were used. Electrochemical impedance spectroscopy showed that the pressure exerted in the MEA manufacturing step had a significant influence with 125 kg cm−2 yielding the highest current density. High temperatures (>80°C) and thin membranes (≈120 μm) showed the best performance while thicker membranes produced higher acid concentration when using the first system. The SO2 concentration in the anode had a significant influence with the over potential increasing with decreasing SO2 concentration. When using the second method, it was found that the SO2 solubility in sulfuric acid is important as the mass transport of the SO2 limits the overall reaction rate. From the two systems tested, the first method, that is, dry SO2 anode and liquid water cathode showed the best operational effectiveness reaching a maximum of 0.32 A cm−2 at 80°C using N115 coated with 1 mgPt cm−2 while the second system under the same conditions achieved a current density of 0.18 A cm−2 when using N117.

Influence of different adsorbates on the efficiency of thermochemical energy storage

Scipedia content — Thu, 01 Jun 2017 14:46:47 +0200

The main influencing parameter on the efficiency of adsorptive thermochemical energy storage is the efficiency of the desorption process, which is influenced by the process conditions, for example, desorption time and desorption temperature, and the working pair (adsorbent–adsorbate). Due to constrained process requirements, for example, hours of sun shine and low desorption temperatures available from a flat plate solar collector (333–373 K), the only possibility to increase the efficiency is to change the working pair. The reference working pair water–zeolite 13X needs high desorption temperatures of 500 K and high heat inputs per mass adsorbent (1080 kJ kg−1) in the desorption process to reach the maximum efficiency of 79 % and maximum energy density of 844 kJ kg−1. Therefore, the goal is to reach efficiencies in the same range as the maximum efficiency of water–zeolite 13X for desorption temperatures lower than 500 K with the usage of different adsorbates. Four systems of alcohol as adsorbate on activated carbon are compared with the reference working pair. The usage of alcohols on activated carbon allows for highly efficient adsorptive storage even at low desorption temperatures between 360 and 450 K. The maximum efficiency is shifted to higher desorption temperatures with increasing carbon chain length of the alcohol. At low desorption temperatures, the energy density and efficiency of methanol, ethanol, and propanol are higher than the energy density of the reference system. Hence, the alcohol systems on activated carbon are viable alternative approaches for regulating these process parameters.

Engineering evaluation of direct methane to methanol conversion

Scipedia content — Thu, 01 Jun 2017 14:46:38 +0200

Investigations into direct methane to methanol conversion are justified based on the avoidance of synthesis gas generation, which accounts for around 60% of the capital cost of synthesis gas to methanol conversion. A significant body of information already exists on the process chemistry, but little has been reported on the engineering of such a process. An engineering evaluation of the process was performed and the potential of this process as a platform technology for small-scale gas-to-liquids (GTL) applications was evaluated. It was found that direct methane to methanol conversion had 35% carbon efficiency and 28% thermal efficiency, which were about half of the process efficiencies of indirect methanol synthesis using synthesis gas. The poor process efficiency was mainly a consequence of the irreversible loss of carbon to CO x during conversion. The direct methane to methanol process also required an air separation unit, which eroded the stated benefit of avoiding a synthesis gas generation step in the process. The utility footprint was typical of GTL processes, with large gas compression duties and cooling duties. Overall, the engineering evaluation indicated there was no benefit to employ direct methane to methanol conversion instead of indirect methanol synthesis (the industry standard), and there was no specific benefit of direct methane to methanol conversion, irrespective of scale, for GTL applications.

Multi angle laser light scattering evaluation of field exposed thermoplastic photovoltaic encapsulant materials

Scipedia content — Thu, 01 Jun 2017 14:46:31 +0200

As creep of polymeric materials is potentially a safety concern for photovoltaic modules, the potential for module creep has become a significant topic of discussion in the development of IEC 61730 and IEC 61215. To investigate the possibility of creep, modules were constructed, using several thermoplastic encapsulant materials, into thin-film mock modules and deployed in Mesa, Arizona. The materials examined included poly(ethylene)-co-vinyl acetate (EVA, including formulations both cross-linked and with no curing agent), polyethylene/polyoctene copolymer (PO), poly(dimethylsiloxane) (PDMS), polyvinyl butyral (PVB), and thermoplastic polyurethane (TPU). The absence of creep in this experiment is attributable to several factors of which the most notable one was the unexpected cross-linking of an EVA formulation without a cross-linking agent. It was also found that some materials experienced both chain scission and cross-linking reactions, sometimes with a significant dependence on location within a module. The TPU and EVA samples were found to degrade with cross-linking reactions dominating over chain scission. In contrast, the PO materials degraded with chain scission dominating over cross-linking reactions. Although we found no significant indications that viscous creep is likely to occur in fielded modules capable of passing the qualification tests, we note that one should consider how a polymer degrades, chain scission or cross-linking, in assessing the suitability of a thermoplastic polymer in terrestrial photovoltaic applications.

Field testing of thermoplastic encapsulants in high-temperature installations

Scipedia content — Thu, 01 Jun 2017 14:46:17 +0200

Recently there has been increased interest in using thermoplastic encapsulant materials in photovoltaic modules, but concerns have been raised about whether these would be mechanically stable at high temperatures in the field. Recently, this has become a significant topic of discussion in the development of IEC 61730 and IEC 61215. We constructed eight pairs of crystalline-silicon modules and eight pairs of glass/encapsulation/glass thin-film mock modules using different encapsulant materials, of which only two were formulated to chemically crosslink. One module set was exposed outdoors with thermal insulation on the back side in Mesa, Arizona, in the summer (hot-dry), and an identical module set was exposed in environmental chambers. High-precision creep measurements (±20 μm) and electrical performance measurements indicate that despite many of these polymeric materials operating in the melt or rubbery state during outdoor deployment, no significant creep was seen because of their high viscosity, lower operating temperature at the edges, and/or the formation of chemical crosslinks in many of the encapsulants with age despite the absence of a crosslinking agent. Only an ethylene-vinyl acetate (EVA) encapsulant formulated without a peroxide crosslinking agent crept significantly. In the case of the crystalline-silicon modules, the physical restraint of the backsheet reduced creep further and was not detectable even for the EVA without peroxide. Because of the propensity of some polymeric materials to crosslink as they age, typical thermoplastic encapsulants would be unlikely to result in creep in the vast majority of installations.

Esterification of hydrolyzed sea mango (Cerbera odollam) oil using various cationic ion exchange resins

Scipedia content — Thu, 01 Jun 2017 14:45:57 +0200

This study investigates the esterification of hydrolyzed sea mango (Cerbera odollam) oil using several cationic ion exchange resins. The best resins were selected based on their performance in a preliminary esterification process. The best resins were then subsequently used in the optimization of the process parameters. The esterification parameters studied were reaction temperature (40–160°C), reaction time (0–5 h), molar ratio of oil to methanol (0.5:1 to 1:14), and catalyst loading (1–14 wt%). Among the resins studied, Amberlyst 15 was found to be the most promising catalyst in the esterification of the hydrolyzed sea mango oil. Moderate reaction temperatures, 60–100°C, were found to be adequate in converting the hydrolyzed sea mango oil into esters. Further investigation revealed that the esterification reaction using the cationic ion exchange resins proceeds at a fast rate, whereby fatty acid methyl esters (FAME) yield of over 80% at moderate reaction temperature was achievable in less than 1 h of reaction time. Small amount of catalyst, which is less than 5 wt%, was also found to be sufficient in catalyzing the esterification process to an acceptable yield.

Al2O3/TiO2 double layer anti-reflection coating film for crystalline silicon solar cells formed by spray pyrolysis

Scipedia content — Thu, 01 Jun 2017 14:45:49 +0200

An Al2O3/TiO2 double layer anti-reflection coating (ARC) film formed by spray pyrolysis was introduced for monocrystalline silicon solar cells as the nonvacuum processing method. The thickness of the Al2O3 layer and TiO2 compact layer was controlled by the volume of deposited precursor solution and confirmed by ellipsometry and scanning electron microscopy. The average photovoltaic properties of photocurrent density (Jsc), open-circuit photovoltage (Voc), fill factor (FF), and photo energy conversion efficiency (η) were 37.0 mA/cm2, 590 mV, 0.712, and 15.5%, respectively. A significant improvement on Jsc and η could be confirmed owing to the Al2O3/TiO2 ARC. The results of Fourier transform infrared (FTIR) spectroscopy and optical simulation with modeling for the reflectance properties confirmed that C-H-based organics remained after the deposition of thin films.

Ozone pretreatment of humid wheat straw for biofuel production

Scipedia content — Thu, 01 Jun 2017 14:45:39 +0200

In an attempt to maximize the amount of ozone reacting with lignin inside humid wheat straw, some of the ozone-reactive lignin degradation products were washed away before a second ozonolysis delignification stage. The total contact time for the two stages was kept the same as that for a one-stage process for comparison. A significant decrease in the Acid Insoluble Lignin (AIL) content of the straw resulted: from 13.04 wt. % (after a 30-min one-stage ozonolysis) to 9.34 wt. % (after a 30-min two-stage ozonolysis, separated by a washing step). This significant improvement was accompanied by an increase in released fermentable sugars from an enzymatic hydrolysis. The yield increased from 60% theoretical sugars to 80%. A further improvement in AIL (down to 7.36 wt. %) and released sugars (up to 90% theoretical) occurred when the moisture content (MC) of the straw entering the second stage was adjusted to the optimum value of the straw entering first stage (45 wt. %, predicted from an experimental design). The authors believe this is the first time results are published for the introduction of a two-stage process separated by a washing step.

A new era of renewable power plants?

Scipedia content — Thu, 01 Jun 2017 14:45:34 +0200

Combining science and engineering for global health and prosperity

Scipedia content — Thu, 01 Jun 2017 14:45:30 +0200

Energy science during industrial transformation

Scipedia content — Thu, 01 Jun 2017 14:44:53 +0200

Discovering new energy solutions

Scipedia content — Thu, 01 Jun 2017 14:44:49 +0200

Capacity assessment of CO2 storage in deep saline aquifers by mineral trapping and the implications for Songliao Basin, Northeast China

Scipedia content — Thu, 01 Jun 2017 14:44:41 +0200

Sequestrating CO2 in deep saline aquifers is maybe the most effective option to mitigate CO2 emission. The storage capacity of CO2 is the key factor for site selection before a project is carried out. Most of the existing methods are for assessment of CO2 sequestered by stratigraphic and structural trapping, as well as residual trapping and solubility trapping. In this study, we used a new method that considers CO2 consumption through geochemical reactions with minerals of reservoir rocks, mainly sandstones. Contribution of storage capacity from carbonate mineral mainly refers to calcite is excluded. That is because lifetime of calcite (the whole time from reaction starting to calcite running out) is very short contrast with geological time-scale or it is a temporary trapping. The geochemical reactions between CO2 and feldspar minerals with thousand-year lifetime are regarded as the permanent methods for trapping CO2. CO2 consumptions by K-feldspar, albite, and anorthite are assessed with volume method based on corresponding geochemical reactions. Storage efficiency factor is also considered as one of the most important parameters in the reaction formula and it depends on specific surface area of minerals contacting with formation water and kinetics of precipitation and dissolution of minerals. We assessed the CO2 storage capacity of mineral trapping in Baokang sedimentary system, south Songliao Basin through the detailed analysis of geological data in this area. The calculated results show the total CO2 storage capacity of mineral trapping of the study area is 457.5–5114.5 Mt and the corresponding storage efficiency factor is 1%. The CO2 consumed by albite makes up more than 60% of the total storage capacity and it is about 30% for anorthite.

Numerical investigation of the effects of dwell time duration in a two-stage injection scheme on exergy terms in an IDI diesel engine by three-dimensional modeling

Scipedia content — Thu, 01 Jun 2017 14:44:26 +0200

Dwell duration of multiple-injection scheme is an important parameter, which makes it possible to shift the tradeoff curve between soot and NOx closer to the origin. In this investigation, therefore, energy and exergy analyses are carried out for various two-step injection schemes in which 25% of the total fuel is injected during the second pulse and the dwell time is increased from 5°CA (crank angle) to 30°CA by 5°CA increments. The calculations are performed for a Lister 8.1 indirect injection (IDI) diesel engine at full load operation. The energy analysis for these schemes is performed during a closed cycle by using a three-dimensional CFD code. The cylinder pressure results for the baseline engine are compared with the corresponding experimental data and they show good agreement. For the exergy analysis, an in-house computational code has been developed, which uses the results of energy analysis in various cases. With crank angle positions and dwell durations set for different injection schemes, various rates of exergy are calculated and the cumulative exergy components are identified separately. The results show that the values of work exergy and exergy efficiency decrease when the dwell duration is changed from 5°CA to 30°CA. Also, there is a sharp change in the exergy parameters when the dwell time reaches 25°CA.

A simplified methodology for estimating solar spectral influence on photovoltaic energy yield using average photon energy

Scipedia content — Thu, 01 Jun 2017 14:44:16 +0200

Nowadays, investors, customers, and even suppliers focus on the bankability of photovoltaic (PV) technologies. However, few studies have investigated the annual net effect of solar spectrum. In this study, we estimate the net effect of the solar spectrum on the annual energy yield of c-Si and a-Si modules by two parameters. One parameter is a direct calculation from spectral factor (SF). The other parameter uses average photon energy (APE) and a regression line or curve. The estimations by the two parameters are quite consistent, whereas there is 1.2% difference between the estimations at most. Therefore, APE would be a useful index to quantify the effect of the solar spectrum.

A bridge to nowhere: methane emissions and the greenhouse gas footprint of natural gas

Scipedia content — Thu, 01 Jun 2017 14:44:08 +0200

In April 2011, we published the first peer-reviewed analysis of the greenhouse gas footprint (GHG) of shale gas, concluding that the climate impact of shale gas may be worse than that of other fossil fuels such as coal and oil because of methane emissions. We noted the poor quality of publicly available data to support our analysis and called for further research. Our paper spurred a large increase in research and analysis, including several new studies that have better measured methane emissions from natural gas systems. Here, I review this new research in the context of our 2011 paper and the fifth assessment from the Intergovernmental Panel on Climate Change released in 2013. The best data available now indicate that our estimates of methane emission from both shale gas and conventional natural gas were relatively robust. Using these new, best available data and a 20-year time period for comparing the warming potential of methane to carbon dioxide, the conclusion stands that both shale gas and conventional natural gas have a larger GHG than do coal or oil, for any possible use of natural gas and particularly for the primary uses of residential and commercial heating. The 20-year time period is appropriate because of the urgent need to reduce methane emissions over the coming 15–35 years.

University of Texas study underestimates national methane emissions at natural gas production sites due to instrument sensor failure

Scipedia content — Thu, 01 Jun 2017 14:44:00 +0200

The University of Texas reported on a campaign to measure methane (CH4) emissions from United States natural gas (NG) production sites as part of an improved national inventory. Unfortunately, their study appears to have systematically underestimated emissions. They used the Bacharach Hi-Flow® Sampler (BHFS) which in previous studies has been shown to exhibit sensor failures leading to underreporting of NG emissions. The data reported by the University of Texas study suggest their measurements exhibit this sensor failure, as shown by the paucity of high-emitting observations when the wellhead gas composition was less than 91% CH4, where sensor failures are most likely, during follow-up testing, the BHFS used in that study indeed exhibited sensor failure consistent with under-reporting of these high emitters. Tracer ratio measurements made by the University of Texas at a subset of sites with low CH4 content further indicate that the BHFS measurements at these sites were too low by factors of three to five. Over 98% of the CH4 inventory calculated from their own data and 41% of their compiled national inventory may be affected by this measurement failure. Their data also indicate that this sensor failure could occur at NG compositions as high as 97% CH4, possibly affecting other BHFS measurement programs throughout the entire NG supply chain, including at transmission sites where the BHFS is used to report greenhouse gas emissions to the United States Environmental Protection Agency Greenhouse Gas Reporting Program (USEPA GHGRP, U.S. 40 CFR Part 98, Subpart W). The presence of such an obvious problem in this high profile, landmark study highlights the need for increased quality assurance in all greenhouse gas measurement programs.

Greenhouse gas emissions from domestic hot water: heat pumps compared to most commonly used systems

Scipedia content — Thu, 01 Jun 2017 14:43:53 +0200

We estimate the emissions of the two most important greenhouse gasses (GHG), carbon dioxide (CO2) and methane (CH4), from the use of modern high-efficiency heat pump water heaters compared to the most commonly used domestic hot water systems: natural gas storage tanks, tankless natural gas demand heaters, electric resistance storage tanks, and tankless electric resistance heaters. We considered both natural gas-powered electric plants and coal-powered plants as the source of the electricity for the heat pumps, the thermal electric storage tanks, and the tankless electric demand heaters. The time-integrated radiative forcing associated with using a heat pump water heater was always smaller than any other means of heating water considered in this study across all time frames including at 20 and 100 years. The estimated amount of CH4 lost during its lifecycle was the most critical factor determining the relative magnitude of the climatic impact. The greatest net climatic benefit within the 20-year time frame was predicted to be achieved when a storage natural gas water heater (the most common system for domestic hot water in the United States) fueled by shale gas was replaced with a high efficiency heat pump water heater powered by coal-generated electricity, the heat pump system powered by renewable electricity would have had an even greater climatic benefit, but was not explicitly modeled in this study. Our analysis provides the first assessment of the GHG footprint associated with using a heat pump water heater, which we demonstrate to be an effective and economically viable way of reducing emissions of GHGs.

Parametric analysis and systems design of dynamic photovoltaic shading modules

Scipedia content — Thu, 01 Jun 2017 14:43:41 +0200

Shading systems improve building energy performance and occupant comfort by controlling glare, natural lighting, and solar gain. Integrating PV (photovoltaics) in shading systems opens new opportunities for BIPV (building integrated photovoltaics) on façades. A key problem of such systems is mutual shading among PV modules as it can lead to electrical mismatch losses and overheating effects. In this work, we present a new modeling framework, which couples parametric 3D with high-resolution electrical modeling of thin-film PV modules to simulate electric energy yield of geometrically complex PV applications. The developed method is able to predict the shading pattern for individual PV modules with high spatio-temporal resolution, which is of great importance for electrical system design. The methodology is applied to evaluate the performance of different dynamic BIPV shading system configurations, as well as its sensitivity to façade orientation and module arrangement. The analysis shows, that there is a trade-off between tracking performance and mutual shading of modules. Distance between modules is a critical parameter influencing the amount of mutual shading and hence limiting solar irradiation and electricity generation of PV shading systems using solar tracking. Planning of module string configuration, PV cell orientation, and location of bypass diodes according to partial shading conditions, reduces electrical mismatch losses and results in significantly higher electricity generation. The integration of parametric 3D and electrical modeling opens new possibilities for PV system design and dynamic control optimization. Though the analysis focuses on BIPV, the method is useful for the planning and operation of solar tracking systems in general.

Turbine design and field development concepts for tidal, ocean, and river applications

Scipedia content — Thu, 01 Jun 2017 14:43:22 +0200

This paper discusses tidal, ocean, and river free turbine functional design parameters and general considerations associated with tidal field developments. A particular focus is on the importance of considering mechanical fatigue and the associated calculation method when designing a turbine for the challenging hydrodynamic environment. The balance between high-fatigue resistances, costs associated with designing components, and potential for reduced turbine efficiency is discussed in regards to the potential energy extracted from a field site. A novel flexible foil vertical turbine concept with high-fatigue resistance, and simple installation and retrieval methods is shown to have a low kWh cost per production output compared to other hydrodynamic turbine concepts. Three possible field development concepts for the flexible foil turbine are described herein for river, ocean current, and tidal applications.

Automatized analysis of IR-images of photovoltaic modules and its use for quality control of solar cells

Scipedia content — Thu, 01 Jun 2017 14:43:10 +0200

It is well known that the performance of solar cells may significantly suffer from local electric defects. Accordingly, infrared thermography (i.p. lock-in thermography) has been intensely applied to identify such defects as hot spots. As an imaging method, this is a fast way of module characterization. However, imaging leads to a huge amount of data, which needs to be investigated. An automatized image analysis would be a very beneficial tool but has not been suggested so far for lock-in thermography images. In this manuscript, we describe such an automatized analysis of solar cells. We first established a robust algorithm for segmentation (or recognition) for both, the PV-module and the defects (hot spots). With this information, we then calculated a parameter from the IR-images, which could be well correlated with the maximal power (Pmpp) of the modules. The proposed automatized method serves as a very useful foundation for faster and more thorough analyses of IR-images and stimulates the further development of quality control on solar modules.

MoS2 as a co-catalyst for photocatalytic hydrogen production from water

Scipedia content — Thu, 01 Jun 2017 14:42:52 +0200

Solar-to-hydrogen conversion based on photocatalytic water splitting is a promising pathway for sustainable hydrogen production. The photocatalytic process requires highly active, inexpensive, and earth-abundant materials as photocatalysts. As a presentative layer-structured transition metal dichalcogenides, molybdenum disulfide (MoS2) is attracting intensive attention due to its unique electro and photo properties. In this article, we comprehensively review the recent research efforts of exploring MoS2 as a co-catalyst for photocatalytic hydrogen production from water, with emphasis on its combination with CdS, CdSe, graphene, carbon nitride, TiO2, and others. It is shown that MoS2–semiconductor composites are promising photocatalysts for hydrogen evolution from water under visible light irradiation.

Fe-Cu metastable material as a mesoporous layer for dye-sensitized solar cells

Scipedia content — Thu, 01 Jun 2017 14:42:33 +0200

This study investigates the performance of dye-sensitized solar cells constructed with a Fe-Cu metastable material as the mesoporous layer on which a natural organic dye is applied. The synthesis of the Fe-Cu material is done via a high throughput process that produces nanosized particles from elemental metallic powders. Xanthophyll is singled out as the organic natural dye of choice among other dyes that were extracted, as it exhibited wider spectral absorptivity in terms of wavelength range and magnitude. Two compact solar cells were constructed and tested, one is a reference cell with a TiO2 working electrode and the other with a Fe-Cu working electrode. The results show a better power conversion efficiency for the Fe-Cu-based solar cell 0.943% compared to 0.638% for the TiO2, and the number of carriers in the former is found to be orders of magnitude higher than the latter (1019 vs. 1032, respectively). A thorough optical, electrical, and thermal analysis of the Fe-Cu material is conducted and used to explain the obtained results.

Review of passive heating/cooling systems of buildings

Scipedia content — Thu, 01 Jun 2017 14:42:06 +0200

In this review, an attempt has been made to analyze passive solar heating and cooling concepts along with their effects on performance of a buildings thermal management. The concepts of Trombe wall, solarium, evaporative cooling, ventilation, radiative cooling, wind tower, earth air heat exchanger, roof pond, solar shading for buildings, and building-integrated photovoltaic thermal (BiPVT) systems are extensively covered in this review. Comparison of results by various heating and cooling concepts has been made. It has been observed that direct heating through double-glazed window saves maximum conventional fuel for thermal heating during winter months. Further, an evaporative cooling is one of the best cooling concepts which is economical too in summer period.

Offshore wind energy potential estimation using UPSCALE climate data

Scipedia content — Thu, 01 Jun 2017 14:41:45 +0200

Offshore and near-shore wind energy is one of the major renewable energy resources, which already make a substantial contribution to the energy supply in Europe. Nevertheless, development is still in the start-up phase, with new projects being planned and implemented continuously. This development needs to be informed, to enable deployment at the most suitable/ideal locations. However, in order to predict the potential energy yield, forecasts have to be made. In this paper the authors present a scoping study. This study uses high-resolution climate data to predict wind speeds at various heights, and various locations along the coast of Mexico. Several techniques for wind extrapolation are explored, alongside a new method based on data analysis. The results show clearly a strong sensitivity to the method chosen, and results have to be interpreted accordingly. Also, the impact of water vapor is shown, using a method that predicts the moist air density at the hub height. The paper indicates that valuable information can be gained from the analyses undertaken, prior to embarking on detailed, targeted studies. The paper concludes with recommendations for further work.

Influence of different SSF conditions on ethanol production from corn stover at high solids loadings

Scipedia content — Thu, 01 Jun 2017 14:41:34 +0200

In this study, three different kinds of simultaneous saccharification and fermentation (SSF) of washed pretreated corn stover with water-insoluble solids (WIS) content of 20% were investigated to find which one resulted in highest ethanol yield at high-solids loadings. The different methods were batch SSF, prehydrolysis followed by batch SSF and fed-batch SSF. Batch-SSF resulted in an ethanol yield of 75–76% and an ethanol concentration of 53 g/L. Prehydrolysis prior to batch SSF did not improve the ethanol yield compared with batch SSF. Fed-batch SSF, on the other hand, increased the yield, independent of the feeding conditions used (79–81%, 57–60 g/L). If the initial amount of solids during fed-batch SSF was lowered, the yield could be improved to some extent. When decreasing the enzyme dosage, the greatest decrease in yield was seen in the fed-batch mode (75%), while lower or the same yield was seen in batch mode with and without prehydrolysis (73%). This resulted in similar ethanol yields in all methods. However, the residence time to achieve the final ethanol yield was shorter using fed-batch. This shows that fed-batch can be a better alternative also at a lower enzyme loading.

High efficiency thin-film amorphous silicon solar cells

Scipedia content — Thu, 01 Jun 2017 14:41:26 +0200

Enhancing light absorption within thin film amorphous silicon (a-Si) solar cells should lead to higher efficiency. This improvement is typically done using various light trapping techniques such as utilizing textured back reflectors for pronounced light scattering within the cell thus achieving higher absorption. It is believed that embedding metallic nanoparticles (MNPs) inside the structure could increase light scattering. However, embedding MNPs can also cause significant structure defects and pronounced efficiency drop as well – it has been indicated by many experiments that disproved this belief. In search of ways to improve efficiency, we have investigated the impact of MNPs size, and location within the solar cell, in addition to the effect of defects, and doping levels on the overall efficiency. On the basis of our 3D multiphysics (optical-electric) modeling, we developed a design guideline for embedding these MNPs and reducing the impact of defects created in the embedding process. The results of simulations were compared to relevant measured data, and it showed a good agreement. Subsequently, models were used to predict performance, and over 30% improvement in solar cell efficiency (~13% is predicted), which is beyond the state of the art. This was predicted by optimizing the size and location of the MNPs and tailoring the doping levels to have better forward light trapping and absorption.

A three-dimensional multiphysics modeling of thin-film amorphous silicon solar cells

Scipedia content — Thu, 01 Jun 2017 14:41:06 +0200

A 3D multiphysics simulation toolbox for thin-film amorphous silicon solar cells has been developed. The simulation is rigorous and is based on developing three modules: first to analyze light propagation using electromagnetic techniques, second to account for charge generation and transportation based on the physics of the semiconductor device, and third including electrode modeling by applying electrostatic techniques. Published results of a P-I-N thin-film amorphous silicon solar cell fabricated on a thick glass and experimentally evaluated was used as a vehicle to validate our 3D multiphysics toolbox and demonstrate its capabilities. The toolbox utilizes COMSOL for solving the partial differential equations describing the three modules, and MATLAB to input data, control the solver, and provides the coupling between the three modules. The developed toolbox was used to investigate both the effect of embedding Metallic Nanoparticles (MNPs) and the impact of defects on the external quantum efficiency. The simulator, besides being rigorous, is suitable to model various types of solar cells (organic, inorganic, thick film, thin film, heterojunction, or plasmonic) as well.

Reservoir modeling for Wabamun lake sequestration project

Scipedia content — Thu, 01 Jun 2017 14:40:41 +0200

A study, entitled “Wabamun Lake Sequestration Project” or “WASP, ” was performed to evaluate large-scale CO2 storage opportunities in the Wabamun area including potential risks. The project examined the feasibility of storing 20 megatons (Mt) of CO2 per year over 50 years. This scale is one order of magnitude larger than the typical benchmark (1 Mt/year) used in academic research and commercial projects that are currently in place or under review. The study was conducted by a group of researchers from several universities as well as industry consultants. This study presents an overview of the reservoir modeling part of this study, which the authors were responsible for. The main objectives of the reservoir modeling for WASP project were as follows: (1) estimation of storage capacity (traditionally, this value is projected based on the available pore space, but we have an additional practical consideration: the maximum amount one can inject within short period of time [~50 years] and within a localized injection area [~30 km × 90 km]), (2) investigation of CO2 plume movement and pressure distribution during and after injection including the effect of formation dip angle on the plume shape and its migration, (3) investigation of the long-term fate of injection associated with free phase CO2 (risks of leakage) and aquifer pressurization (possible geomechanical changes and related phenomena), (4) investigation of the phase behavior of H2S initially available and dissolved in brine during CO2 sequestration process. The WASP reservoir modeling study mentioned above led to a few important findings. The most important one is that, when CO2 is being injected into a sour aquifer, initially dissolved H2S will release into the expanding CO2 plume and accumulate at the leading edge of the plume. Also, the large-scale injection scheme (20 Mt/year), which requires multi well injectors, provides very different pressure response compared to a one well (1 Mt/year) scenario.

Liquinert quartz crucible for the growth of multicrystalline Si ingots

Scipedia content — Thu, 01 Jun 2017 14:40:30 +0200

The growth of a multicrystalline silicon (mc-Si) ingot for solar cell applications was attempted using a Liquinert quartz crucible. A mc-Si ingot was also grown in a quartz crucible coated with Si3N4 powder for comparison with that from the Liquinert quartz crucible. The mc-Si ingot grown in the Liquinert quartz crucible had a shinier surface which has few impurity particles and higher minority carrier lifetime than the mc-Si ingot grown in a quartz crucible coated with Si3N4 powder. These results indicate that contamination with impurities was reduced with the Liquinert quartz crucible, therefore, this crucible has the potential to be a powerful tool for the production of high-quality mc-Si ingots for solar cell applications.

Effect of oxomolybdate species dispersion on direct methanol oxidation to dimethoxymethane over MoO x /TiO2 catalysts

Scipedia content — Thu, 01 Jun 2017 14:40:21 +0200

The one-step selective oxidation of methanol to dimethoxymethane (DMM) was demonstrated over titania-supported molybdenum oxide catalysts, containing different amounts of molybdenum and prepared using two different impregnation techniques, namely wet impregnation and incipient wetness impregnation. The corresponding catalysts exhibited both acidic and redox properties, which are necessary for the oxidation of methanol to formaldehyde with subsequent condensation of the latter with excess methanol to finally yield DMM. The formation of well-dispersed polyoxomolybdate species on the catalyst surface was evidenced using IR-Raman, X-ray diffraction, and nitrogen physisorption. Varying the amount of these polyoxomolydate species was associated with a modulation of the acidic and redox properties, as shown by NH3-TPD and H2-TPR. With respect to the catalytic performances, the best balance between acid and redox properties was observed over the samples containing 8 wt.% Mo, which corresponds to a theoretical MoO x species coverage close to a monolayer.

Optimization and comparison analysis for application of PV panels in three villages

Scipedia content — Thu, 01 Jun 2017 14:40:12 +0200

In recent years, research about the application and optimization of PV panels has grown rapidly. Especially for stand-alone solar systems there have been some problems related to first stages of design and application. Finding the optimum slope of PV panels in order to maximize the absorbed solar radiation is considered as one of the major obstacles. Although in Malaysia there have been some research works about finding of optimal tilt angle, however, this research work aims to start investigation about slope of PV panels for three villages without electricity and prior research. The Liu and Jordan model is applied to find the monthly optimal tilt angle and fixed tilt angle for the application of solar energy in these rural locations. The results demonstrate that the optimal tilt angle in these locations is less than 5°.

Oxyfuel combustion in rotary kiln lime production

Scipedia content — Thu, 01 Jun 2017 14:40:03 +0200

The purpose of this article is to study the impact of oxyfuel combustion applied to a rotary kiln producing lime. Aspects of interest are product quality, energy efficiency, stack gas composition, carbon dioxide emissions, and possible benefits related to carbon dioxide capture. The method used is based on multicomponent chemical equilibrium calculations to predict process conditions. A generic model of a rotary kiln for lime production was validated against operational data and literature. This predicting simulation tool is used to calculate chemical compositions for different recirculation cases. The results show that an oxyfuel process could produce a high-quality lime product. The new process would operate at a lower specific energy consumption thus having also a reduced specific carbon dioxide emission per ton of product ratio. Through some processing, the stack gas from the new process could be suitable for carbon dioxide transport and storage or utilization. The main conclusion of this paper is that lime production with an oxyfuel process is feasible but still needs further study.

Tip speed ratio control of a 200 kW VAWT with synchronous generator and variable DC voltage

Scipedia content — Thu, 01 Jun 2017 14:39:53 +0200

A novel control method for a fixed-pitch variable speed wind turbine is introduced and experimental results are presented. The measured absorbed power and rotational speed, together with a look-up table for the aerodynamic efficiency, are used to estimate the wind speed reaching the turbine as well as the tip speed ratio. Thereby, the control is independent on wind speed measurements and the wind turbine itself is used as an anemometer. Tip speed ratio control is implemented by comparing the estimated tip speed ratio to a reference value and adjusting the DC voltage level accordingly. Tip speed ratio control benefits from that the aerodynamic efficiency hardly varies with changing tip speed ratio when close to its optimum value. Experimental results from a 200 kW vertical axis wind turbine are presented. The voltage from the permanent magnet generator is passively rectified and the alternating DC voltage is then inverted, filtered, transformed, and grid connected. The estimated wind speed is compared with the measured wind speed. The absorbed power when tip speed ratio control has been implemented is shown. It is concluded that the presented control method works and some future improvements are discussed.

Cyclical hydrogen storage and retention in polyaniline

Scipedia content — Thu, 01 Jun 2017 14:39:45 +0200

Hydrogen adsorption in porous nanostructured polyaniline (PANI) has been investigated to determine its potential as a hydrogen storage media. Residual gas analysis and thermogravimetric analysis were used to investigate the cyclical hydrogen adsorption in PANI. A hydrogen storage capacity of up to 3 wt % was obtained by charging the polymers at up to 3.0 × 106 Pa hydrogen at elevated temperature. Multiple charge and discharge cycles have been shown, with good retention beyond 106 sec.

Renewable energy auctions in South Africa outshine feed-in tariffs

Scipedia content — Thu, 01 Jun 2017 14:39:38 +0200

South Africas Renewable Energy Independent Power Producer Procurement Program has run four competitive tenders/auctions since 2011, which have seen US$19 billion in private investment, and electricity prices of wind power falling by 46% and solar PV electricity prices by 71%, in nominal terms. Competitive tenders were introduced after an unsuccessful attempt to implement feed-in tariffs. The tenders incorporated standard, nonnegotiable contract documents, including 20-year Power Purchase Agreements and an Implementation Agreement whereby the Government of South Africa back-stops IPP payments by the national utility, Eskom. All of these projects have reached financial close to date and some are already delivering power to the grid. The financing success has been due in part to the requirements for commercial banks to undertake a thorough due diligence of projects prior to bids being offered. The details of the policy package described may be useful for other policy makers in countries developing policies for renewable energy deployment.

Comprehensive study of performance degradation of field-mounted photovoltaic modules in India

Scipedia content — Thu, 01 Jun 2017 14:39:27 +0200

The All India Survey of Photovoltaic Module Reliability 2014 is an enhanced version of the survey conducted in the previous year, with detailed characterization of PV modules including current-voltage, infrared and electroluminescence imaging, visual inspection, insulation resistance test and interconnect breakage test. More than a thousand modules were inspected in the field and the main results of the survey are presented in this paper. The average Pmax degradation rate for the so-called ‘good’ modules (Group X) is 1.33%/year which is higher than that commonly projected by manufacturers, and widely employed in financial calculations. Modules falling in the ‘not-so-good’ category (Group Y) show even higher degradation rates, and it is at least partly due to higher number of micro-cracks in the modules, and increased degradation of the packaging materials like encapsulant, backsheet, etc. Modules in ‘Hot’ climates degrade faster than modules in the ‘Non-Hot’ climates. Degradation in fill factor is the primary cause for performance degradation in the young modules (ages

Performance analysis of a tower solar collector-aided coal-fired power generation system

Scipedia content — Thu, 01 Jun 2017 14:39:07 +0200

In this paper, a tower solar collector-aided coal-fired power generation (TSCACPG) system is proposed and studied in order to save the fossil energy and protect the environment. The integration scheme of tower solar collector and conventional coal-fired power plant is proposed. Based on the simulation platform TRNSYS, the TSCACPG system model is established and the dynamic performance of the TSCACPG system with the operating mode of coal saving is studied. The TSCACPG system performances of 1 day and 1 year are all discussed by using the DNI data of typical year in Chinese typical city of Dunhuang. Then, the sensitivity analysis of the TSCACPG system is carried out by changing the heliostat field scale (the size of the molten salt tower also changes accordingly). The annual performance of the TSCACPG system is also acquired. In consideration of the economic costs, the heliostat field area with the maximum annual solar-to-electric efficiency is selected as the optimal value. The results show that, for the case studied, the optimal heliostat field area is 101, 400 m2, and the maximum annual solar-to-electric efficiency is 16.74%. And under the optimal situation, the standard coal consumption rate of the original coal-fired power plant is reduced from 301.5 g/kWh to 294.5 g/kWh.

Design and experimental execution of a microcontroller (μC)-based smart dual-axis automatic solar tracking system

Scipedia content — Thu, 01 Jun 2017 14:38:51 +0200

Detail analysis of microcontroller (μC)-based smart dual-axis automatic solar tracking system utilizable for different purpose is presented in this paper. Working of the proposed smart tracking system is based on the automatic rotation of photovoltaic (PV) panel depending on the intensity of sun light. It will help in maintaining the alignment of PV panels with the Sunlight to obtain maximum solar power at any instance. Intensity of sunlight on a particular alignment of solar PV panel varies throughout the day. As the intensity of light on PV panel decreases the proposed smart tracking system has the intelligence to automatically redirect the panel alignment to get maximum intensity of light. Four Light Dependent Resistor (LDR) sensors are placed on the surface of the PV panel to detect the intensity of light. Two servomotors are employed in the back side of PV panel system to align the panel with maximum luminous intensity. Design and construction of the proposed tracking system is presented to measure the efficiency over the fixed PV panel. Experimental results indicate that the power output of the PV system, using the proposed tracking system is increased up to 19.73% compare to the traditional fixed PV panel. The efficiency of the proposed design is considerably higher and comparable to the existing design which has the average efficiency around 12–15%.

Experimental study of the effect of inhibitors in wax precipitation by different techniques

Scipedia content — Thu, 01 Jun 2017 14:38:40 +0200

The blocking problems in equipment and flowlines caused by precipitation of wax solids is a well-known problem and large research efforts have been focused on developing procedures dealing with wax deposition. Among the different alternatives, the use of chemicals is frequently used to inhibit wax precipitation. The presence of these compounds modifies the size and/or the shape of the paraffinic solids, thus affecting their flow behavior and cold properties. In this work, a methodology based on different experimental techniques was developed to study the effect of different additives on the crude oil behavior at low temperature. Four commercial inhibitors were added to three crude oils in different concentrations. The effect of the inhibitors on wax precipitation was studied using differential scanning calorimetry (DSC) and cross-polarized microscopy (CPM). Obtained results for wax appearance temperature (WAT) using DSC do not show remarkable differences regarding the presence of inhibitor. However, CPM analyses revealed differences in both size and shape of paraffin solids. The results obtained in this work reveal that in some cases the inhibitor does not modify the WAT values, but the morphology of the precipitated particles. In these cases, it is necessary to combine DSC and CPM analyses to obtain reliable results.

Enhanced biogas production from coffee pulp through deligninocellulosic photocatalytic pretreatment

Scipedia content — Thu, 01 Jun 2017 14:38:32 +0200

Production of biogas utilizing agricultural wastes is one of the most demanding technologies for generating energy in sustainable manner considering environmental concerns. However, though the agricultural wastes are available in abundance, the technologies used for the production of biogas such as biological and thermochemical processes are not very efficient. In the present article, we describe a process for the production of biogas from coffee pulp utilizing Cu/TiO2 as an efficient photocatalyst in its solar photocatalytic pretreatment, producing biogas of high caloric value at enhanced rate. The pretreatment process enhances the coffee pulp–cattle manure codigestion, producing increased amounts of methane, propane, and other combustible components of biogas. The photocatalytic pretreatment was performed using 10%Cu/TiO2 as photocatalyst, bubbling air as oxidizing agent, and solar radiation as light source. The process enhances the degradation rate of lignocellulosic components of coffee pulp, consequently increasing the biogas production through anaerobic codigestion. The mechanism of photocatalytic degradation of lignocelluloses has been discussed. The results presented in this work indicate the photocatalytic pretreatment is a useful process to increase biogas generation from lignocelluloses-rich natural wastes.

Estimating the specific chemical exergy of municipal solid waste

Scipedia content — Thu, 01 Jun 2017 14:38:18 +0200

A new model for predicting the specific chemical exergy of municipal solid waste (MSW) is presented, the model is based on the content of carbon, hydrogen, oxygen, nitrogen, sulfur, and chlorine on a dry ash-free basis (daf). The proposed model was obtained from estimations of the higher heating value (HHV) and standard entropy of MSW using statistical analysis. The ultimate analysis of 56 different parts of MSW was used for the derivation of the HHV expression. In addition, 30 extra parts were used for validation. One hundred and seventeen relevant organic substances that represented the main constituents in MSW were used for derivation of the standard entropy of solid waste. The substances were divided into different waste fractions, and the standard entropies of each waste fraction and for the complete mixture were calculated. The specific chemical exergy of inorganic matter in the waste was also investigated by considering the inorganic compounds in the ash. However, as a result of the extremely low value calculated, the exergy of inorganic matter was ignored. The results obtained from the HHV model show a good correlation with the measured values and are comparable with other recent and previous models. The correlation of the standard entropy of the complete waste mixture is less accurate than the correlations of each individual waste fraction. However, the correlations give similar results for the specific chemical exergy, indicating that HHV has a greater impact when estimating the specific exergy of solid waste than entropy.

Technical mapping of solar PV for ISM-an approach toward green campus

Scipedia content — Thu, 01 Jun 2017 14:38:05 +0200

This paper aims toward the first step for green campus approach for Indian School of Mines (ISM) campus. Comparative study of the performances for nine different commercialized solar panels made of Maxeon Cell Technology, HIT (Heterojunction with Intrinsic Thin layer), monocrystalline silicon (Mono C-Si), polycrystalline silicon (Poly C-Si), Micromorph, SCHOTT, amorphous silicon (a-Si), CIGS, CdTe technologies in the environmental condition of ISM are presented in this paper. This system suggests to supply the daytime electricity demand of ISM campus as well as efficient use of the huge roof areas of different buildings to setting up the photovoltaic plant. This system ensures a daily mean reduction of 8 MWh electricity consumption from grid. The outcome of this study is that a superior performance is noted for modules made of amorphous silicon technology under the typical temperature variant and dry environmental condition of ISM campus.

Developing new perspectives on the energy trilemma

Scipedia content — Thu, 01 Jun 2017 14:38:00 +0200

The energy group of SCI (Society of Chemical Industry) was host for an event on 28th March 2017 at SCI Headquarters in London (UK) with a meeting on the important topic of the energy trilemma (sustainable, affordable and secure supply of energy). Alexandra Carrick gives an overview of the event.

Heterogeneous and homogenous catalysts for hydrogen generation by hydrolysis of aqueous sodium borohydride (NaBH4) solutions

Scipedia content — Thu, 01 Jun 2017 14:37:54 +0200

It is clear that in order to satisfy global energy demands whilst maintaining sustainable levels of atmospheric greenhouse gases, alternative energy sources are required. Due to its high chemical energy density and the benign by-product of its combustion reactions, hydrogen is one of the most promising of these. However, methods of hydrogen storage such as gas compression or liquefaction are not suitable for portable or automotive applications due to their low hydrogen storage densities. Accordingly, much research activity has been focused on finding higher density hydrogen storage methods. One such method is to generate hydrogen via the hydrolysis of aqueous sodium borohydride (NaBH4) solutions, and this has been heavily studied since the turn of the century due to its high theoretical hydrogen storage capacity (10.8 wt%) and relatively safe operation in comparison to other chemical hydrides. This makes it very attractive for use as a hydrogen generator, in particular for portable applications. Major factors affecting the hydrolysis reaction of aqueous NaBH4 include the performance of the catalyst, reaction temperature, NaBH4 concentration, stabilizer concentration, and the volume of the reaction solution. Catalysts based on noble metals, in particular ruthenium (Ru) and platinum (Pt), have been shown to be particularly efficient at rapid generation of hydrogen from aqueous NaBH4 solutions. However, given the scarcity and expense of such metals, a transition metal-based catalyst would be a desirable alternative, and thus much work has been conducted using cobalt (Co) and nickel (Ni)-based materials to attempt to source a practical option. “Metal free” NaBH4 hydrolysis can also be achieved by the addition of aqueous acids such as hydrochloric acid (HCl) to solid NaBH4. This review summarizes the various catalysts which have been reported in the literature for the hydrolysis of NaBH4.

An old solution to a new problem? Hydrogen generation by the reaction of ferrosilicon with aqueous sodium hydroxide solutions

Scipedia content — Thu, 01 Jun 2017 14:37:46 +0200

The chemical hydrogen storage properties of ferrosilicon were investigated. A hydrogen yield of ~4.75 wt.% (with respect to the mass of ferrosilicon) was estimated by the reaction of varying quantities of ferrosilicon with 5 mL of 40 wt.% sodium hydroxide solution. The reaction of ferrosilicon with aqueous sodium hydroxide solution to form hydrogen was found to have an activation energy of 90.5 kJ mol−1 by means of an Arrhenius plot. It was observed that the induction period of the hydrogen generation reaction varies exponentially with temperature. Although this combination of high activation energy and a lengthy induction period at low temperatures reduces the attractiveness of ferrosilicon for portable hydrogen storage applications unless methods can be developed to accelerate the onset and rate of hydrogen generation, its low cost and widespread availability make it attractive for further studies focused on higher temperature stationary applications.

Numerical computation of a large-scale jet fire of high-pressure hydrogen in process plant

Scipedia content — Thu, 01 Jun 2017 14:37:32 +0200

Due to numerous hazardous chemicals to handle, the process plant industry has a higher risk of fire, explosion, and toxic release than other industries. Reviewing the accidents at process plants in the past, it is clear that fire accidents occur with the highest frequency, leading this study to consider accidental fire scenarios at process plants. For the scenario of an incident, a jet fire involving a massive amount of hydrogen gas to be processed or delivered at the process plant has been selected. The analysis of incident outcome resulting from the hydrogen jet fire has been implemented through the computational fluid dynamics simulation methodology Kameleon FireEx. Based on the outcome of this simulation, the consequences of a jet fire with high temperature and heat radiation are analyzed and evaluated. In addition, the results from Phast ver. 7.11 simulation for the same scenario are presented for comparison and further validation.

Energy harvesting for assistive and mobile applications

Scipedia content — Thu, 01 Jun 2017 14:36:52 +0200

Technology advances have enabled modification of the size and shape of the electronic components to the microscale, with commensurate scaling down of their power requirements to milliwatts and microwatt range. Consequently, many complex electronic systems and devices such as wearable medical and autonomous devices consume power in the range less than 200 μW, and wireless sensor networks in the range μW to 100 mW are operated on battery power. Due to the salient limitations of battery power, such as longevity of charge and where applicable, the requirement for periodic recharging, possibilities for utilization of autonomous energy sources is critical for operation of such devices. Ambient energy sources, such as vibrations (1 μW to 20 mW), motion (wide range in power outputs), temperature gradient (0.5–10 mW), radiofrequency waves (>180 μW/cm2), light (100 μW/cm2 to 100 mW/cm2), acoustics (0.003–0.11 μW/cm2), and many other, have the potential to directly power the electronic device. Ambient energy harvesting, when used separately or in conjunction with batteries, will enhance the longevity of equipment operations requiring portable or autonomous power supply. This paper reviews the state of the art in energy-harvesting techniques, power conversion, and characterization of mini- and microscale self-sustaining power generation systems in the range 600 μW to 5 W, specifically focusing on low-power system applications, for personal assistive and mobile technology devices.

Photovoltaics: between a bright outlook and uncertainty

Scipedia content — Thu, 01 Jun 2017 14:36:44 +0200

There is “breakneck” growth in the global photovoltaics market, with the global market of photovoltaic cells growing by about 47% in 2009, 72% in 2010, and 74% in 2011. Global installed capacity in 2011 was three times more than 2009. Italy and Germany are leading with a 57% share of the global market. Costs are dropping rapidly and photovoltaic (PV) power generation is an attractive option for investors. Increasing support of European Union (EU) for renewable energy in general and PV aims to diversify sources of energy and reduce reliance on fossil fuels, on nuclear and on imported energy. Energy security is an important dimension for the EU. Almost all experts agree that there is no single technology that will provide a sustainable global supply of cleaner energy. However, the scale, the cost of the change needed and supporting policy and legislation are often subject to debate. High costs could be counterbalanced by economic yields from new businesses, the creation of new jobs, and economic growth from clean energy investments. The current situation in which Germany and Italy account for almost 2/3 of global PV market growth and, also, the strong reliance on supporting policies is unstable. If PV power generation is to continue growing, the balance of development will have to shift to new markets – both inside and outside of Europe. Fixed price policy is a game to be played with caution. This article highlights examples of Spain, Italy, and Germany that illustrate that without robust policy the system can be easily misbalanced. When – or even if – photovoltaic power does become cheap enough to compete without subsidies against more established energy sources, depends upon a number of uncertainties, including the continuing political will to provide financial support, and how readily developing nations such as China and India embrace renewable energies.

Potential induced degradation of n-type crystalline silicon solar cells with p front junction

Scipedia content — Thu, 01 Jun 2017 14:36:36 +0200

N-type silicon-based solar cells are currently being used for achieving high efficiency. However, most of the photovoltaic modules already constructed are based on p-type silicon solar cells, and there are few studies on potential induced degradation (PID) in n-type solar cells. In this study, we investigated PID in n-type silicon solar cells with a front p+ emitter. Further, the PID characteristics of n-type solar cells are compared with those of p-type solar cells. The electrical properties of PID in solar cells are observed with the light I-V, quantum efficiency (QE), and electroluminescence (EL). The possible causes for the change in the external quantum efficiency (EQE) after PID are interpreted using PC1D and are discussed by comparing the experimental results with the simulation results.