Abstract

Glass-fibre reinforced polymer (GRP) composite materials are the most widely adopted amongst fibrereinforced polymer composites globally, with approximately 1 million tons produced annually in the EU alone. GRP’s find very wide use and application in a number of industrial sectors (e.g. land & waterborne transport1 , marine, construction) due to their excellent balance between good performance and low cost compared to fibre reinforced polymers utilising other commercially available fibres (e.g. carbon, aramid). Particularly in marine applications, durability of composites and their ability to exhibit unchanged performance and stability in a marine context and environment is a crucial factor in order to select the most appropriate combination of polymer matrix and reinforcement. Ideally, a composite would retain its mechanical and thermo-mechanical profile even when exposed to a marine environment for extended periods. In this work, we conducted an extensive comparative study of the water absorption behavior and retention of mechanical properties of a group of GRP composite laminates manufactured with a range of infusible thermosetting and thermoplastics resins. Sample preparation for water immersion studies was according to ASTM D5229. This study was part of a comprehensive down-selection of commercially available resins in terms of their suitability for shipbuilding applications, as part of the EU H2020 project FIBRESHIP2 . All laminates were manufactured by Vacuum-Assisted Resin Transfer Moulding (VARTM; the most relevant manufacturing technique in shipbuilding) with a range of state-of-the-art thermosetting resins (Urethane acrylate Crestapol 1210, Epoxy SR1125, Bio-epoxy Supersap CLR, Phenolic Cellobond J2027X) and a novel infusible acrylic thermoplastic resin (Acrylic Elium 150). The reinforcement of choice for each laminate was a unidirectional glass fabric of 996 gsm. A selection of relevant properties of the laminates with different resin systems is presented in this paper including fibre volume fraction, apparent interlaminar shear strength (dry and wet condition), flexural strength (dry and wet condition) and flexural modulus (dry and wet condition). For the wet condition, samples were immersed in distilled water for 28 days at 35 oC (wet state) in accordance with classification society guidelines. The quality of the laminates (void content, fibre-matrix adhesion) was examined by scanning electron microscopy on fracture surfaces. The effects of water absorption on the microstructure, mechanical, thermal & thermomechanical properties of the laminates were studied. The average water absorption percentage varied across all resins systems from 0.19 to 1.37% in the interlaminar-shear specimens, and from 0.25 to 1.59% in the flexure specimens. The phenolic laminate was the one absorbing most water in both cases but the mechanical properties were relatively unaffected. Fibre volume fraction was in the range 0.56 to 0.6 for all of the laminates. The majority of the tested GRP laminates showed good retention of their flexural properties and interlaminar shear strength under the testing conditions. The laminate that appeared to be most adversely affected was the infusible thermoplastic, showing a reduction in flexural strength and interlaminar shear strength of 17.3% and 37.5%, respectively (in comparison to the dry state values). However, the water absorption for the Elium 150 was not excessive, ranging from 0.40 to 0.42% for the ILSS and flexure samples, respectively.

References: 1 Summerscales J, Marine applications of advanced fibre reinforced composites, Woodhead Publishing, Cambridge, 2016 2 H2020 project FIBRESHIP, funded by the European Commission under GA 723360 (www.fibreship.eu)

Abstract

The industry decarbonization has become in a fundamental challenge for the industries such as automotive or wind power. In this way, the structural components lightening is one of the principal issues for material manufacturers. For this objective, the composites are a competitive alternative, due to their unique relation between their strength and weight. Among the different structural composite part fabrication processes, liquid composite moulding (LCM) is one of the most interesting, due to its efficiency in terms of costs, time and energy consumption.

In this sense, resins with fast cure and low viscosity are gaining attention, among them polyurethanes are of particular interest.

This family of polymers is characterized by its great versatility, among them high-performance thermosetting polyurethanes (PUR). The advantages offered by PUR-based technology are great fatigue resistance, low viscosity and fast cure. However, the commonly used PUR’s for structural applications have some environmentally drawbacks, such as their components petrochemical origin and their low recyclability. For this reason, the aim of this work was the development of a more sustainable PUR formulation with the required mechanical properties for structural applications and suitable processability for LCM processes. Because of that, this work has focused on the analysis, synthesis and characterization of new PUR formulations and also the manufacturing process simulation and optimization.

Abstract

CS2-LPA-IADP-WP1.2.5. Advanced Rear End Manufacturing is an European project, inside of the CleanSky2 research program of the European Union Horizon 2020 (Grant Agreement nº 945583). This work package focuses on design, manufacturing and testing of new technologies for the manufacturing of aeronautical structures, integrating different elements, at the rear end of an aircraft.

The work presented here shows the manufacturing process developed to obtain a full-scale demonstrator of a rear end section of the fuselage in prepreg carbon fiber composite material, integrating stiffeners, contour frames and skin in one-shot. The omega section stiffeners are made by automatic lay-up and forming, integrate them fresh into the demonstrator. The contour frames are also automatically lay-up and formed, carrying out a semi-curing cycle (for which a manufacturing test campaign has been necessary and different curing degree studies). The integration of these semi-cured frames in the demonstrator combines the advantages of a cobonded integration (without rivets) and the simplification of the tools respect to fresh elementals, since the final thickness has already been consolidated. The automatic lay-up of the skin is carried out on a tool where the fresh stiffeners and the semi-cured frames are located. Finally, the curing cyle is done in the autoclave, obtaining the full-scale highly integrated fuselage demonstrator.

All the technologies developed in this demonstrator allow automation within an industrial environment with high production rates. 

Abstract

One of the weak points of the structures made of carbon fibre reinforced materials and thermosetting matrix is its mechanical impact behavior. In order to improve it, materials reinforced with carbon fiber and thermoplastic resin matrix are under study. In addition to the mechanical properties there are other factors to consider before introducing any structural material in the manufacturing of an aircraft, such as its lightning strike behavior. Materials properties that influence this behavior are mainly electrical, thermal and also mechanical; and these properties are modified from thermoset resins to thermoplastics. Within the Clean Sky program Airbus Defense and Space has carried out preliminary tests on flat panels manufactured by Fidamc with a carbon fibre reinforced material and thermoplastic resin matrix with two different configurations, both layout and additional (with and without metallization) The tests objective was the evaluation and comparison of the damages obtained after a lightning strike in flat panels made of traditional materials (thermoset matrix) with those made with new thermoplastic matrix materials. Both the mechanical damage and the temperatures generated in the material (using a thermal camera during the test) were analyzed in order to compare the thermal behavior of the thermoplastic matrix against the thermostable. This article shows the work done as well as results and conclusions.