While fiber reinforced polymer (FRP) composites are widely utilized in structural components due to their favorable mechanical properties, delamination between reinforcing plies remains a major problem, weakening the composite structure and limiting more widespread applications of FRPs. Carbon nanotubes (CNTs) carry the promise of enhancing this poor out-of-plane mechanical performance, although their integration has been challenging. In this work, macroscopic CNT veils with controlled nano-meso structure were drawn from the gas-phase using a semi-industrial process and then integrated into woven carbon fiber/epoxy matrix composites utilizing a facile and scalable approach. Interlaminar fracture toughness (ILFT) of the resulting composites was determined in Mode-I (opening mode) test. Additionally, crack propagation and interlaminar toughening mechanisms were systematically analyzed by means of optical microscope, SEM, and Raman analysis. The results showed that mode I ILFT was improved as much as 60% when interleaving as-received fluffy CNT veils and also revealed that interlaminar crossing between CNT veil/CF interfaces is of paramount importance in toughening mechanism.
Abstract
While fiber reinforced polymer (FRP) composites are widely utilized in structural components due to their favorable mechanical properties, delamination between reinforcing plies remains a major problem, weakening the composite structure and limiting more widespread applications [...]